Spectroscopy of jet-cooled AlMn and trends in the electronic structure of the 3 d transition metal aluminides

Jet-cooled diatomic AlMn has been spectroscopically investigated and is shown to possess a 5Πi ground state deriving from the Al (3s23p1,2P0)+Mn (3d54s2,6S) separated atom limit. This implies that the aluminum atom favors a 3pπ approach to the manganese atom, a result that is in agreement with previ...

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Veröffentlicht in:The Journal of chemical physics 1994-10, Vol.101 (8), p.6500-6511
Hauptverfasser: Behm, Jane M., Morse, Michael D.
Format: Artikel
Sprache:eng
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