Pressure tuning spectroscopy of the low-frequency Raman spectrum of liquid amides
The effect of hydrostatic pressure up to 4 kbar on the low frequency Raman spectrum of hydrogen bonded (formamide, N-methylformamide, N-ethylformamide, and N-methylpropionamide) and nonhydrogen bonded (N,N′-dimethylformamide and N,N′-dimethylacetamide) liquid amides is reported. A shift of ca. 4.0 c...
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| Veröffentlicht in: | The Journal of chemical physics 1993-10, Vol.99 (8), p.5736-5741 |
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| container_end_page | 5741 |
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| container_issue | 8 |
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| container_title | The Journal of chemical physics |
| container_volume | 99 |
| creator | GOOSSENS, K SMELLER, L HEREMANS, K |
| description | The effect of hydrostatic pressure up to 4 kbar on the low frequency Raman spectrum of hydrogen bonded (formamide, N-methylformamide, N-ethylformamide, and N-methylpropionamide) and nonhydrogen bonded (N,N′-dimethylformamide and N,N′-dimethylacetamide) liquid amides is reported. A shift of ca. 4.0 cm−1/kbar is observed for the nonhydrogen bonded amides. For the hydrogen bonded amides the shift is ca. 2.0–3.0 cm−1/kbar. The difference may be explained by the compression of the hydrogen bond which affects the librational motion of the molecules. |
| doi_str_mv | 10.1063/1.465924 |
| format | Article |
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A shift of ca. 4.0 cm−1/kbar is observed for the nonhydrogen bonded amides. For the hydrogen bonded amides the shift is ca. 2.0–3.0 cm−1/kbar. The difference may be explained by the compression of the hydrogen bond which affects the librational motion of the molecules.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.465924</identifier><identifier>CODEN: JCPSA6</identifier><language>eng</language><publisher>Woodbury, NY: American Institute of Physics</publisher><subject>Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Lattice dynamics ; Physics ; Vibrational states in disordered systems</subject><ispartof>The Journal of chemical physics, 1993-10, Vol.99 (8), p.5736-5741</ispartof><rights>1994 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c320t-7be1bad8cbde54254c5382869c2fa868925f9df9916c6516ccf7a5a93f25de1c3</citedby><cites>FETCH-LOGICAL-c320t-7be1bad8cbde54254c5382869c2fa868925f9df9916c6516ccf7a5a93f25de1c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3799977$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>GOOSSENS, K</creatorcontrib><creatorcontrib>SMELLER, L</creatorcontrib><creatorcontrib>HEREMANS, K</creatorcontrib><title>Pressure tuning spectroscopy of the low-frequency Raman spectrum of liquid amides</title><title>The Journal of chemical physics</title><description>The effect of hydrostatic pressure up to 4 kbar on the low frequency Raman spectrum of hydrogen bonded (formamide, N-methylformamide, N-ethylformamide, and N-methylpropionamide) and nonhydrogen bonded (N,N′-dimethylformamide and N,N′-dimethylacetamide) liquid amides is reported. A shift of ca. 4.0 cm−1/kbar is observed for the nonhydrogen bonded amides. For the hydrogen bonded amides the shift is ca. 2.0–3.0 cm−1/kbar. 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| ispartof | The Journal of chemical physics, 1993-10, Vol.99 (8), p.5736-5741 |
| issn | 0021-9606 1089-7690 |
| language | eng |
| recordid | cdi_crossref_primary_10_1063_1_465924 |
| source | AIP Digital Archive |
| subjects | Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Lattice dynamics Physics Vibrational states in disordered systems |
| title | Pressure tuning spectroscopy of the low-frequency Raman spectrum of liquid amides |
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