Neutron diffraction studies of ices III and IX on under-pressure and recovered samples

Detailed structural studies using powder neutron diffraction have been carried out on ices III and IX on both under-pressure and recovered samples. The incomplete hydrogen ordering in recovered ice IX first observed by La Placa et al. is confirmed, and our studies suggest similar orderings for the u...

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Veröffentlicht in:The Journal of chemical physics 1993-03, Vol.98 (6), p.4878-4888
Hauptverfasser: LONDONO, J. D, KUHS, W. F, FINNEY, J. L
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creator LONDONO, J. D
KUHS, W. F
FINNEY, J. L
description Detailed structural studies using powder neutron diffraction have been carried out on ices III and IX on both under-pressure and recovered samples. The incomplete hydrogen ordering in recovered ice IX first observed by La Placa et al. is confirmed, and our studies suggest similar orderings for the under-pressure and recovered phases. Sample history was observed to influence the lattice constants of ice IX, an effect which could relate to hydrogen ordering. There is an indication that ice III is not fully disordered, a conclusion which would be consistent with independent thermodynamic measurements.
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subjects Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Water, oxides, hydroxides, peroxides
title Neutron diffraction studies of ices III and IX on under-pressure and recovered samples
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