Vibrational and rotational relaxation times of solvated molecular ions

Infrared pump–probe and infrared polarization spectroscopy have been used to measure the vibrational relaxation times (T1) of the antisymmetric stretching mode and the reorientation times (TR) for N3−, NCS−, and NCO− in D2O and/or methanol. For N3−, experiments were also conducted in H2O and hexamet...

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Veröffentlicht in:	The Journal of chemical physics 1993-04, Vol.98 (7), p.5499-5507
Hauptverfasser:	LI, M, OWRUTSKY, J, SARISKY, M, CULVER, J. P, YODH, A, HOCHSTRASSER, R. M
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic and molecular physics Effects of atomic and molecular interactions on electronic structure Electronic structure of atoms, molecules and their ions: theory Exact sciences and technology Physics Time-dependent phenomena: excitation and relaxation processes, and reaction rates
Online-Zugang:	Volltext
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