Rate coefficient expressions for reactions of molecules in 2Π electronic states at low temperatures
Analytical rate coefficient expressions are derived at low temperatures for the fast reactions of a 2Π molecule with each of a structureless ion, a 2Π molecule, and a 1Σ molecule. The procedure, based on classical capture theory, involves perturbation theory and simple long-range electrostatic poten...
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| Veröffentlicht in: | The Journal of chemical physics 1993, Vol.98 (1), p.420-426 |
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| container_end_page | 426 |
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| container_issue | 1 |
| container_start_page | 420 |
| container_title | The Journal of chemical physics |
| container_volume | 98 |
| creator | WICKHAM, A. G CLARY, D. C |
| description | Analytical rate coefficient expressions are derived at low temperatures for the fast reactions of a 2Π molecule with each of a structureless ion, a 2Π molecule, and a 1Σ molecule. The procedure, based on classical capture theory, involves perturbation theory and simple long-range electrostatic potential terms for the various interactions. The open-shell nature of the reactant molecules is fully considered. The predictions made are contrasted with those quoted previously for the equivalent reactions involving 1Σ molecules and interesting differences in the temperature dependencies of the rate coefficient are highlighted. |
| doi_str_mv | 10.1063/1.464635 |
| format | Article |
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The predictions made are contrasted with those quoted previously for the equivalent reactions involving 1Σ molecules and interesting differences in the temperature dependencies of the rate coefficient are highlighted.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.464635</identifier><identifier>CODEN: JCPSA6</identifier><language>eng</language><publisher>Woodbury, NY: American Institute of Physics</publisher><subject>Atomic and molecular collision processes and interactions ; Atomic and molecular physics ; Exact sciences and technology ; Physics ; Scattering of atoms, molecules and ions</subject><ispartof>The Journal of chemical physics, 1993, Vol.98 (1), p.420-426</ispartof><rights>1993 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1015-c05199aa76b5c534e92af36f508214f20cd96fb574c1b78978352a1a1563c9153</citedby><cites>FETCH-LOGICAL-c1015-c05199aa76b5c534e92af36f508214f20cd96fb574c1b78978352a1a1563c9153</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,4010,27900,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=4557005$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>WICKHAM, A. 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The procedure, based on classical capture theory, involves perturbation theory and simple long-range electrostatic potential terms for the various interactions. The open-shell nature of the reactant molecules is fully considered. The predictions made are contrasted with those quoted previously for the equivalent reactions involving 1Σ molecules and interesting differences in the temperature dependencies of the rate coefficient are highlighted.</abstract><cop>Woodbury, NY</cop><pub>American Institute of Physics</pub><doi>10.1063/1.464635</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-9606 |
| ispartof | The Journal of chemical physics, 1993, Vol.98 (1), p.420-426 |
| issn | 0021-9606 1089-7690 |
| language | eng |
| recordid | cdi_crossref_primary_10_1063_1_464635 |
| source | AIP Digital Archive |
| subjects | Atomic and molecular collision processes and interactions Atomic and molecular physics Exact sciences and technology Physics Scattering of atoms, molecules and ions |
| title | Rate coefficient expressions for reactions of molecules in 2Π electronic states at low temperatures |
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