Photoionization mass spectrometry of CH2S and HCS

The transient species CH2S and HCS were studied by photoionization mass spectrometry. They were prepared in situ from CH3SH by sequential hydrogen abstraction with fluorine atoms. CH2S was also prepared by pyrolysis of CH3SCl and CH3SSCH3. The photoion yield curve of CH2S displays an abrupt threshol...

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Veröffentlicht in:The Journal of chemical physics 1993-02, Vol.98 (4), p.2568-2579
Hauptverfasser: RUSCIC, B, BERKOWITZ, J
Format: Artikel
Sprache:eng
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