Diffusion-limited reactions in spherical cavities
We study a quenching reaction occurring at sinks within a spherical cavity and at the cavity surface. One may think of reactions at these two, distinct locations as two, coupled reactive channels. Reactions of the type D*+A→D+A are studied in the limit of nondilute A, present at both locations, and...
Gespeichert in:
| Veröffentlicht in: | The Journal of chemical physics 1992-06, Vol.96 (12), p.8840-8852 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 8852 |
|---|---|
| container_issue | 12 |
| container_start_page | 8840 |
| container_title | The Journal of chemical physics |
| container_volume | 96 |
| creator | BUG, A. L. R GROSSMAN, E. L MORGAN, D. D |
| description | We study a quenching reaction occurring at sinks within a spherical cavity and at the cavity surface. One may think of reactions at these two, distinct locations as two, coupled reactive channels. Reactions of the type D*+A→D+A are studied in the limit of nondilute A, present at both locations, and dilute D, present within the cavity. We use a Monte Carlo algorithm to compute mean rates, pseudo-first-order rates and branching ratios, and compare with results obtained by assuming that the two reactive channels operate in parallel. The ratio of activities of the two channels are varied; static and moving sinks are studied. We discuss an application to the determination of pore structure by NMR (nuclear magnetic resonance). |
| doi_str_mv | 10.1063/1.462241 |
| format | Article |
| fullrecord | <record><control><sourceid>pascalfrancis_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1063_1_462241</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>5499400</sourcerecordid><originalsourceid>FETCH-LOGICAL-c254t-b2058648b471b636b328fbfd738bd4ccb65657b4420c09dd5adb851e90d7799a3</originalsourceid><addsrcrecordid>eNo9j8tKxEAURBtRMI6Cn5CFCzcZ7-13L2V8woAbXYd-YksmE7qj4N87EnFVUByKOoRcIqwRJLvBNZeUcjwiDYI2nZIGjkkDQLEzEuQpOav1AwBQUd4QvMspfda8H7sh7_IcQ1ui9fOhqG0e2zq9x5K9HVpvv_KcYz0nJ8kONV785Yq8Pdy_bp667cvj8-Z223kq-Nw5CkJLrh1X6CSTjlGdXAqKaRe4904KKZTjnIIHE4KwwWmB0UBQyhjLVuR62fVlX2uJqZ9K3tny3SP0v6o99ovqAb1a0MnWw9VU7Ohz_ecFN4YDsB8fH1Gm</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Diffusion-limited reactions in spherical cavities</title><source>AIP_美国物理联合会期刊回溯（NSTL购买）</source><creator>BUG, A. L. R ; GROSSMAN, E. L ; MORGAN, D. D</creator><creatorcontrib>BUG, A. L. R ; GROSSMAN, E. L ; MORGAN, D. D</creatorcontrib><description>We study a quenching reaction occurring at sinks within a spherical cavity and at the cavity surface. One may think of reactions at these two, distinct locations as two, coupled reactive channels. Reactions of the type D*+A→D+A are studied in the limit of nondilute A, present at both locations, and dilute D, present within the cavity. We use a Monte Carlo algorithm to compute mean rates, pseudo-first-order rates and branching ratios, and compare with results obtained by assuming that the two reactive channels operate in parallel. The ratio of activities of the two channels are varied; static and moving sinks are studied. We discuss an application to the determination of pore structure by NMR (nuclear magnetic resonance).</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.462241</identifier><identifier>CODEN: JCPSA6</identifier><language>eng</language><publisher>Woodbury, NY: American Institute of Physics</publisher><subject>Chemistry ; Exact sciences and technology ; General and physical chemistry ; Theory of reactions, general kinetics ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>The Journal of chemical physics, 1992-06, Vol.96 (12), p.8840-8852</ispartof><rights>1992 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c254t-b2058648b471b636b328fbfd738bd4ccb65657b4420c09dd5adb851e90d7799a3</citedby><cites>FETCH-LOGICAL-c254t-b2058648b471b636b328fbfd738bd4ccb65657b4420c09dd5adb851e90d7799a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=5499400$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>BUG, A. L. R</creatorcontrib><creatorcontrib>GROSSMAN, E. L</creatorcontrib><creatorcontrib>MORGAN, D. D</creatorcontrib><title>Diffusion-limited reactions in spherical cavities</title><title>The Journal of chemical physics</title><description>We study a quenching reaction occurring at sinks within a spherical cavity and at the cavity surface. One may think of reactions at these two, distinct locations as two, coupled reactive channels. Reactions of the type D*+A→D+A are studied in the limit of nondilute A, present at both locations, and dilute D, present within the cavity. We use a Monte Carlo algorithm to compute mean rates, pseudo-first-order rates and branching ratios, and compare with results obtained by assuming that the two reactive channels operate in parallel. The ratio of activities of the two channels are varied; static and moving sinks are studied. We discuss an application to the determination of pore structure by NMR (nuclear magnetic resonance).</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Theory of reactions, general kinetics</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1992</creationdate><recordtype>article</recordtype><recordid>eNo9j8tKxEAURBtRMI6Cn5CFCzcZ7-13L2V8woAbXYd-YksmE7qj4N87EnFVUByKOoRcIqwRJLvBNZeUcjwiDYI2nZIGjkkDQLEzEuQpOav1AwBQUd4QvMspfda8H7sh7_IcQ1ui9fOhqG0e2zq9x5K9HVpvv_KcYz0nJ8kONV785Yq8Pdy_bp667cvj8-Z223kq-Nw5CkJLrh1X6CSTjlGdXAqKaRe4904KKZTjnIIHE4KwwWmB0UBQyhjLVuR62fVlX2uJqZ9K3tny3SP0v6o99ovqAb1a0MnWw9VU7Ohz_ecFN4YDsB8fH1Gm</recordid><startdate>19920615</startdate><enddate>19920615</enddate><creator>BUG, A. L. R</creator><creator>GROSSMAN, E. L</creator><creator>MORGAN, D. D</creator><general>American Institute of Physics</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19920615</creationdate><title>Diffusion-limited reactions in spherical cavities</title><author>BUG, A. L. R ; GROSSMAN, E. L ; MORGAN, D. D</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c254t-b2058648b471b636b328fbfd738bd4ccb65657b4420c09dd5adb851e90d7799a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1992</creationdate><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Theory of reactions, general kinetics</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>BUG, A. L. R</creatorcontrib><creatorcontrib>GROSSMAN, E. L</creatorcontrib><creatorcontrib>MORGAN, D. D</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>BUG, A. L. R</au><au>GROSSMAN, E. L</au><au>MORGAN, D. D</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Diffusion-limited reactions in spherical cavities</atitle><jtitle>The Journal of chemical physics</jtitle><date>1992-06-15</date><risdate>1992</risdate><volume>96</volume><issue>12</issue><spage>8840</spage><epage>8852</epage><pages>8840-8852</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><coden>JCPSA6</coden><abstract>We study a quenching reaction occurring at sinks within a spherical cavity and at the cavity surface. One may think of reactions at these two, distinct locations as two, coupled reactive channels. Reactions of the type D*+A→D+A are studied in the limit of nondilute A, present at both locations, and dilute D, present within the cavity. We use a Monte Carlo algorithm to compute mean rates, pseudo-first-order rates and branching ratios, and compare with results obtained by assuming that the two reactive channels operate in parallel. The ratio of activities of the two channels are varied; static and moving sinks are studied. We discuss an application to the determination of pore structure by NMR (nuclear magnetic resonance).</abstract><cop>Woodbury, NY</cop><pub>American Institute of Physics</pub><doi>10.1063/1.462241</doi><tpages>13</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-9606 |
| ispartof | The Journal of chemical physics, 1992-06, Vol.96 (12), p.8840-8852 |
| issn | 0021-9606 1089-7690 |
| language | eng |
| recordid | cdi_crossref_primary_10_1063_1_462241 |
| source | AIP_美国物理联合会期刊回溯（NSTL购买） |
| subjects | Chemistry Exact sciences and technology General and physical chemistry Theory of reactions, general kinetics Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | Diffusion-limited reactions in spherical cavities |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T18%3A53%3A52IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pascalfrancis_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Diffusion-limited%20reactions%20in%20spherical%20cavities&rft.jtitle=The%20Journal%20of%20chemical%20physics&rft.au=BUG,%20A.%20L.%20R&rft.date=1992-06-15&rft.volume=96&rft.issue=12&rft.spage=8840&rft.epage=8852&rft.pages=8840-8852&rft.issn=0021-9606&rft.eissn=1089-7690&rft.coden=JCPSA6&rft_id=info:doi/10.1063/1.462241&rft_dat=%3Cpascalfrancis_cross%3E5499400%3C/pascalfrancis_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |