The viscosity dependence and reaction coordinate for isomerization of cis-stilbene

Femtosecond spectroscopic methods are used to study the dynamics following optical excitation of cis-stilbene molecules in hydrocarbon solvents. Transient absorption spectra of cis-stilbene over the range 320–1100 nm are reported. The anisotropies of these transients permit the assignment of the var...

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Veröffentlicht in:	The Journal of chemical physics 1990-07, Vol.93 (2), p.1041-1053
Hauptverfasser:	ABRASH, S, REPINEC, S, HOCHSTRASSER, R. M
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic and molecular physics Barrier heights (internal rotation, inversion, rotational isomerism, conformational dynamics) Exact sciences and technology Molecular properties and interactions with photons Physics Properties of molecules and molecular ions
Online-Zugang:	Volltext
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