Analysis of CH2  a ̃ 1 A 1 (1,0,0) and (0,0,1) Coriolis-coupled states, a ̃ 1 A 1– X ̃ 3 B 1 spin–orbit coupling, and the equilibrium structure of CH2  a ̃ 1 A 1 state

The symmetric and antisymmetric stretch spectra of ã 1A1 CH2 are measured with Doppler-limited resolution by infrared flash-kinetic spectroscopy between 2600 and 3050 cm−1. The spectra are significantly perturbed by spin–orbit interactions between near-resonant levels of X̃ 3B1 in both lower and up...

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Veröffentlicht in:	The Journal of chemical physics 1989-12, Vol.91 (11), p.6566-6578
Hauptverfasser:	Petek, Hrvoje, Nesbitt, David J., Darwin, David C., Ogilby, Peter R., Moore, C. Bradley, Ramsay, D. A.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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