Vibrationally mediated photodissociation of t-butyl hydroperoxide: vibrational overtone spectroscopy and photodissociation dynamics

Vibrationally mediated photodissociation is a two-photon technique for studying the spectroscopy and photodissociation dynamics of highly vibrationally excited molecules. In these experiments, a highly vibrationally excited t-butyl hydroperoxide (t-BuOOH) molecule, prepared by excitation in the regi...

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Veröffentlicht in:	J. Chem. Phys.; (United States) 1989-06, Vol.90 (11), p.6266-6274
Hauptverfasser:	LIKAR, M. D, BAGGOTT, J. E, CRIM, F. F
Format:	Artikel
Sprache:	eng
Schlagworte:	400500 - Photochemistry ALKOXY RADICALS Atomic and molecular physics BUTOXY RADICALS CHEMICAL BONDS CHEMICAL REACTION YIELD CHEMICAL REACTIONS CONFORMATIONAL CHANGES DECOMPOSITION ENERGY LEVELS ENERGY-LEVEL TRANSITIONS Exact sciences and technology EXCITATION EXCITED STATES HYDROXYL RADICALS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Molecular properties and interactions with photons MULTI-PHOTON PROCESSES ORGANIC COMPOUNDS ORGANIC OXYGEN COMPOUNDS PHOTOCHEMICAL REACTIONS PHOTOLYSIS Photon interactions with molecules Physics RADICALS VIBRATIONAL STATES YIELDS
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