Near-infrared bound-free emission from the NaK molecule

We report the observation of bound–free emission corresponding to the lowest triplet transition 1 3Π→1 3Σ+ of the NaK molecule. In the experiment, specific levels of the upper triplet state were populated directly from the ground state by virtue of spin–orbit induced perturbations between the 1 3Π0...

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Veröffentlicht in:The Journal of chemical physics 1988-05, Vol.88 (10), p.6013-6021
Hauptverfasser: HUENNEKENS, J, LOZA, A, MASTERS, M, SANDO, K. M
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container_title The Journal of chemical physics
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creator HUENNEKENS, J
LOZA, A
MASTERS, M
SANDO, K. M
description We report the observation of bound–free emission corresponding to the lowest triplet transition 1 3Π→1 3Σ+ of the NaK molecule. In the experiment, specific levels of the upper triplet state were populated directly from the ground state by virtue of spin–orbit induced perturbations between the 1 3Π0 and 2 1Σ+ states. Oscillations in the fluorescence spectra between 1.1 and 1.6 μm reflect the probability distribution (wave function squared) in the bound upper state. We have also carried out quantum mechanical simulations of the fluorescence spectra, based on recent ab initio calculations of the relevant potential curves. These simulations verify the identification of this near-infrared emission and provide a critical test for the calculated potentials.
doi_str_mv 10.1063/1.454493
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subjects Atomic and molecular physics
Exact sciences and technology
Fluorescence and phosphorescence
radiationless transitions, quenching (intersystem crossing, internal conversion)
Molecular properties and interactions with photons
Physics
title Near-infrared bound-free emission from the NaK molecule
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