High-resolution photoionization spectrum of water molecules in a supersonic beam

We have obtained high-resolution (∼1.5 cm−1) photoionization spectra of supersonically cooled (Trot∼50 K) H2O and D2O in the 1000–900 Å range. The light source, which used the technique of frequency tripling in a pulsed free jet of gas, is described briefly. Spectra are rotationally resolved. Vibrat...

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Veröffentlicht in:	J. Chem. Phys.; (United States) 1988-02, Vol.88 (4), p.2249-2263
Hauptverfasser:	PAGE, R. H, LARKIN, R. J, SHEN, Y. R, LEE, Y. T
Format:	Artikel
Sprache:	eng
Schlagworte:	640301 - Atomic, Molecular & Chemical Physics- Beams & their Reactions 640302 - Atomic, Molecular & Chemical Physics- Atomic & Molecular Properties & Theory ATOMIC AND MOLECULAR PHYSICS AUTOIONIZATION BEAMS CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS DISSOCIATION ENERGY LEVELS Exact sciences and technology EXCITED STATES FLUID FLOW HEAVY WATER HYDROGEN COMPOUNDS IONIZATION IONIZATION POTENTIAL LIFETIME MOLECULAR BEAMS Molecular properties and interactions with photons OXYGEN COMPOUNDS PHOTOIONIZATION Photon interactions with molecules Physics PREDISSOCIATION RYDBERG STATES SUPERSONIC FLOW WATER
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