Evidence of structural isomerism in small niobium clusters
The reactivity of Nb clusters with nitrogen and deuterium was studied using a pulsed laser vporization source coupled to a fast flow reactor. The relative reactivity of the various clusters was determined by monitoring the depletion of the cluster ion signal as a function of reactant flow rate. A ki...
Gespeichert in:
| Veröffentlicht in: | J. Chem. Phys.; (United States) 1988-03, Vol.88 (6), p.4095-4098 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 4098 |
|---|---|
| container_issue | 6 |
| container_start_page | 4095 |
| container_title | J. Chem. Phys.; (United States) |
| container_volume | 88 |
| creator | HAMRICK, Y TAYLOR, S LEMIRE, G. W FU, Z.-W SHUI, J.-C MORSE, M. D |
| description | The reactivity of Nb clusters with nitrogen and deuterium was studied using a pulsed laser vporization source coupled to a fast flow reactor. The relative reactivity of the various clusters was determined by monitoring the depletion of the cluster ion signal as a function of reactant flow rate. A kinetic analysis of the chemisorption is given. The geometrical isomerism of the cluster ions and its relationship to reactivity is discussed.(AIP) |
| doi_str_mv | 10.1063/1.453813 |
| format | Article |
| fullrecord | <record><control><sourceid>pascalfrancis_osti_</sourceid><recordid>TN_cdi_crossref_primary_10_1063_1_453813</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>7079792</sourcerecordid><originalsourceid>FETCH-LOGICAL-c281t-a59981a897324818dbc6c663f52b1865cd4aeba69aafd50580e4309518d78d373</originalsourceid><addsrcrecordid>eNo90EtLxDAUhuEgCo6j4E8o4sJNx5OmubkTGS8w4EbXIT1NMdLLkJMK_ntHKq6-zcO3eBm75LDhoMQt39RSGC6O2IqDsaVWFo7ZCqDipVWgTtkZ0ScAcF3VK3a3_YptGDEUU1dQTjPmOfm-iDQNIUUaijgWNPi-L8Y4NXEeCuxnyiHROTvpfE_h4m_X7P1x-_bwXO5en14e7nclVobn0ktrDffGalHVhpu2QYVKiU5WDTdKYlv70Hhlve9aCdJAqAVYeZDatEKLNbtafifK0RHGHPADp3EMmJ2stdbCHtDNgjBNRCl0bp_i4NO34-B-wzjuljAHer3QvSf0fZf8iJH-vQZtta3ED9VWYJ0</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Evidence of structural isomerism in small niobium clusters</title><source>AIP Digital Archive</source><creator>HAMRICK, Y ; TAYLOR, S ; LEMIRE, G. W ; FU, Z.-W ; SHUI, J.-C ; MORSE, M. D</creator><creatorcontrib>HAMRICK, Y ; TAYLOR, S ; LEMIRE, G. W ; FU, Z.-W ; SHUI, J.-C ; MORSE, M. D ; Department of Chemistry, University of Utah, Salt Lake City, Utah 84112</creatorcontrib><description>The reactivity of Nb clusters with nitrogen and deuterium was studied using a pulsed laser vporization source coupled to a fast flow reactor. The relative reactivity of the various clusters was determined by monitoring the depletion of the cluster ion signal as a function of reactant flow rate. A kinetic analysis of the chemisorption is given. The geometrical isomerism of the cluster ions and its relationship to reactivity is discussed.(AIP)</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.453813</identifier><identifier>CODEN: JCPSA6</identifier><language>eng</language><publisher>Woodbury, NY: American Institute of Physics</publisher><subject>400201 - Chemical & Physicochemical Properties ; AGGLOMERATION ; Atomic and molecular clusters ; Atomic and molecular physics ; CHEMICAL REACTIONS ; CHEMISORPTION ; DEUTERIUM ; ELEMENTS ; Exact sciences and technology ; HYDROGEN ISOTOPES ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; ISOTOPES ; LIGHT NUCLEI ; METALS ; MOLECULAR STRUCTURE ; MOLECULES ; NIOBIUM ; NITROGEN ; NONMETALS ; NUCLEI ; ODD-ODD NUCLEI ; Physics ; REACTIVITY ; SEPARATION PROCESSES ; SIZE ; SORPTION ; SORPTIVE PROPERTIES ; STABLE ISOTOPES ; Studies of special atoms, molecules and their ions; clusters ; SURFACE PROPERTIES ; SURFACES ; TRANSITION ELEMENTS</subject><ispartof>J. Chem. Phys.; (United States), 1988-03, Vol.88 (6), p.4095-4098</ispartof><rights>1989 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c281t-a59981a897324818dbc6c663f52b1865cd4aeba69aafd50580e4309518d78d373</citedby><cites>FETCH-LOGICAL-c281t-a59981a897324818dbc6c663f52b1865cd4aeba69aafd50580e4309518d78d373</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,886,27929,27930</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=7079792$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/5477739$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>HAMRICK, Y</creatorcontrib><creatorcontrib>TAYLOR, S</creatorcontrib><creatorcontrib>LEMIRE, G. W</creatorcontrib><creatorcontrib>FU, Z.-W</creatorcontrib><creatorcontrib>SHUI, J.-C</creatorcontrib><creatorcontrib>MORSE, M. D</creatorcontrib><creatorcontrib>Department of Chemistry, University of Utah, Salt Lake City, Utah 84112</creatorcontrib><title>Evidence of structural isomerism in small niobium clusters</title><title>J. Chem. Phys.; (United States)</title><description>The reactivity of Nb clusters with nitrogen and deuterium was studied using a pulsed laser vporization source coupled to a fast flow reactor. The relative reactivity of the various clusters was determined by monitoring the depletion of the cluster ion signal as a function of reactant flow rate. A kinetic analysis of the chemisorption is given. The geometrical isomerism of the cluster ions and its relationship to reactivity is discussed.(AIP)</description><subject>400201 - Chemical & Physicochemical Properties</subject><subject>AGGLOMERATION</subject><subject>Atomic and molecular clusters</subject><subject>Atomic and molecular physics</subject><subject>CHEMICAL REACTIONS</subject><subject>CHEMISORPTION</subject><subject>DEUTERIUM</subject><subject>ELEMENTS</subject><subject>Exact sciences and technology</subject><subject>HYDROGEN ISOTOPES</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>ISOTOPES</subject><subject>LIGHT NUCLEI</subject><subject>METALS</subject><subject>MOLECULAR STRUCTURE</subject><subject>MOLECULES</subject><subject>NIOBIUM</subject><subject>NITROGEN</subject><subject>NONMETALS</subject><subject>NUCLEI</subject><subject>ODD-ODD NUCLEI</subject><subject>Physics</subject><subject>REACTIVITY</subject><subject>SEPARATION PROCESSES</subject><subject>SIZE</subject><subject>SORPTION</subject><subject>SORPTIVE PROPERTIES</subject><subject>STABLE ISOTOPES</subject><subject>Studies of special atoms, molecules and their ions; clusters</subject><subject>SURFACE PROPERTIES</subject><subject>SURFACES</subject><subject>TRANSITION ELEMENTS</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1988</creationdate><recordtype>article</recordtype><recordid>eNo90EtLxDAUhuEgCo6j4E8o4sJNx5OmubkTGS8w4EbXIT1NMdLLkJMK_ntHKq6-zcO3eBm75LDhoMQt39RSGC6O2IqDsaVWFo7ZCqDipVWgTtkZ0ScAcF3VK3a3_YptGDEUU1dQTjPmOfm-iDQNIUUaijgWNPi-L8Y4NXEeCuxnyiHROTvpfE_h4m_X7P1x-_bwXO5en14e7nclVobn0ktrDffGalHVhpu2QYVKiU5WDTdKYlv70Hhlve9aCdJAqAVYeZDatEKLNbtafifK0RHGHPADp3EMmJ2stdbCHtDNgjBNRCl0bp_i4NO34-B-wzjuljAHer3QvSf0fZf8iJH-vQZtta3ED9VWYJ0</recordid><startdate>19880315</startdate><enddate>19880315</enddate><creator>HAMRICK, Y</creator><creator>TAYLOR, S</creator><creator>LEMIRE, G. W</creator><creator>FU, Z.-W</creator><creator>SHUI, J.-C</creator><creator>MORSE, M. D</creator><general>American Institute of Physics</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19880315</creationdate><title>Evidence of structural isomerism in small niobium clusters</title><author>HAMRICK, Y ; TAYLOR, S ; LEMIRE, G. W ; FU, Z.-W ; SHUI, J.-C ; MORSE, M. D</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-a59981a897324818dbc6c663f52b1865cd4aeba69aafd50580e4309518d78d373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1988</creationdate><topic>400201 - Chemical & Physicochemical Properties</topic><topic>AGGLOMERATION</topic><topic>Atomic and molecular clusters</topic><topic>Atomic and molecular physics</topic><topic>CHEMICAL REACTIONS</topic><topic>CHEMISORPTION</topic><topic>DEUTERIUM</topic><topic>ELEMENTS</topic><topic>Exact sciences and technology</topic><topic>HYDROGEN ISOTOPES</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>ISOTOPES</topic><topic>LIGHT NUCLEI</topic><topic>METALS</topic><topic>MOLECULAR STRUCTURE</topic><topic>MOLECULES</topic><topic>NIOBIUM</topic><topic>NITROGEN</topic><topic>NONMETALS</topic><topic>NUCLEI</topic><topic>ODD-ODD NUCLEI</topic><topic>Physics</topic><topic>REACTIVITY</topic><topic>SEPARATION PROCESSES</topic><topic>SIZE</topic><topic>SORPTION</topic><topic>SORPTIVE PROPERTIES</topic><topic>STABLE ISOTOPES</topic><topic>Studies of special atoms, molecules and their ions; clusters</topic><topic>SURFACE PROPERTIES</topic><topic>SURFACES</topic><topic>TRANSITION ELEMENTS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>HAMRICK, Y</creatorcontrib><creatorcontrib>TAYLOR, S</creatorcontrib><creatorcontrib>LEMIRE, G. W</creatorcontrib><creatorcontrib>FU, Z.-W</creatorcontrib><creatorcontrib>SHUI, J.-C</creatorcontrib><creatorcontrib>MORSE, M. D</creatorcontrib><creatorcontrib>Department of Chemistry, University of Utah, Salt Lake City, Utah 84112</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Chem. Phys.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>HAMRICK, Y</au><au>TAYLOR, S</au><au>LEMIRE, G. W</au><au>FU, Z.-W</au><au>SHUI, J.-C</au><au>MORSE, M. D</au><aucorp>Department of Chemistry, University of Utah, Salt Lake City, Utah 84112</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Evidence of structural isomerism in small niobium clusters</atitle><jtitle>J. Chem. Phys.; (United States)</jtitle><date>1988-03-15</date><risdate>1988</risdate><volume>88</volume><issue>6</issue><spage>4095</spage><epage>4098</epage><pages>4095-4098</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><coden>JCPSA6</coden><abstract>The reactivity of Nb clusters with nitrogen and deuterium was studied using a pulsed laser vporization source coupled to a fast flow reactor. The relative reactivity of the various clusters was determined by monitoring the depletion of the cluster ion signal as a function of reactant flow rate. A kinetic analysis of the chemisorption is given. The geometrical isomerism of the cluster ions and its relationship to reactivity is discussed.(AIP)</abstract><cop>Woodbury, NY</cop><pub>American Institute of Physics</pub><doi>10.1063/1.453813</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-9606 |
| ispartof | J. Chem. Phys.; (United States), 1988-03, Vol.88 (6), p.4095-4098 |
| issn | 0021-9606 1089-7690 |
| language | eng |
| recordid | cdi_crossref_primary_10_1063_1_453813 |
| source | AIP Digital Archive |
| subjects | 400201 - Chemical & Physicochemical Properties AGGLOMERATION Atomic and molecular clusters Atomic and molecular physics CHEMICAL REACTIONS CHEMISORPTION DEUTERIUM ELEMENTS Exact sciences and technology HYDROGEN ISOTOPES INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOTOPES LIGHT NUCLEI METALS MOLECULAR STRUCTURE MOLECULES NIOBIUM NITROGEN NONMETALS NUCLEI ODD-ODD NUCLEI Physics REACTIVITY SEPARATION PROCESSES SIZE SORPTION SORPTIVE PROPERTIES STABLE ISOTOPES Studies of special atoms, molecules and their ions clusters SURFACE PROPERTIES SURFACES TRANSITION ELEMENTS |
| title | Evidence of structural isomerism in small niobium clusters |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-16T06%3A12%3A57IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pascalfrancis_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Evidence%20of%20structural%20isomerism%20in%20small%20niobium%20clusters&rft.jtitle=J.%20Chem.%20Phys.;%20(United%20States)&rft.au=HAMRICK,%20Y&rft.aucorp=Department%20of%20Chemistry,%20University%20of%20Utah,%20Salt%20Lake%20City,%20Utah%2084112&rft.date=1988-03-15&rft.volume=88&rft.issue=6&rft.spage=4095&rft.epage=4098&rft.pages=4095-4098&rft.issn=0021-9606&rft.eissn=1089-7690&rft.coden=JCPSA6&rft_id=info:doi/10.1063/1.453813&rft_dat=%3Cpascalfrancis_osti_%3E7079792%3C/pascalfrancis_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |