Generalized van der Waals analysis of critical drops and cavities in simple fluids

The classical treatment of critical drops and cavities in metastable bulk fluids is reexamined and extended by the use of simple generalized van der Waals (GvdW) approximations. Step function particle density profiles are assumed but the density of the nucleating phase is allowed to vary. The effect...

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Veröffentlicht in:	The Journal of chemical physics 1987, Vol.87 (1), p.675-686
Hauptverfasser:	HOOPER, M. A, NORDHOLM, S
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Colloidal state and disperse state Exact sciences and technology General and physical chemistry Physical and chemical studies. Granulometry. Electrokinetic phenomena
Online-Zugang:	Volltext
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