Dimension dependence of correlation energies in two-electron atoms

Correlation energies (CEs) for two-electron atom ground states have been computed as a function of the dimensionality of space D. The classical limit D→∞ and hyperquantum limit D→1 are qualitatively different and especially easy to solve. In hydrogenic units, the CE for any two-electron atom is foun...

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Veröffentlicht in:	The Journal of chemical physics 1987-03, Vol.86 (6), p.3512-3521
Hauptverfasser:	LOESER, J. G, HERSCHBACH, D. R
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic and molecular physics Electron correlation calculations for atoms and molecules Electronic structure of atoms, molecules and their ions: theory Exact sciences and technology Physics
Online-Zugang:	Volltext
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