Spin-correlated crystal field parameters for lanthanide ions substituted into LaCl3

Fits to spectral energy levels for Ho3+:LaCl3 and Gd3+:LaCl3 establish, for the first time, empirical values of the lanthanide spin-correlated crystal field parameters. The fitted rank 6 parameters are consistent with the superposition model analysis and provide the solution to a long standing probl...

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Veröffentlicht in:	The Journal of chemical physics 1984-01, Vol.81 (11), p.4959-4962
Hauptverfasser:	CROSSWHITE, H, NEWMAN, D. J
Format:	Artikel
Sprache:	eng
Schlagworte:	Condensed matter: electronic structure, electrical, magnetic, and optical properties Crystal and ligand fields Electron states Exact sciences and technology Level splitting and interactions Physics
Online-Zugang:	Volltext
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