Spin-correlated crystal field parameters for lanthanide ions substituted into LaCl3

Spin-correlated crystal field parameters for lanthanide ions substituted into LaCl3

Fits to spectral energy levels for Ho3+:LaCl3 and Gd3+:LaCl3 establish, for the first time, empirical values of the lanthanide spin-correlated crystal field parameters. The fitted rank 6 parameters are consistent with the superposition model analysis and provide the solution to a long standing probl...

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Veröffentlicht in:The Journal of chemical physics 1984-01, Vol.81 (11), p.4959-4962
Hauptverfasser: CROSSWHITE, H, NEWMAN, D. J
Format: Artikel
Sprache:eng
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Condensed matter: electronic structure, electrical, magnetic, and optical properties
Crystal and ligand fields
Electron states
Exact sciences and technology
Level splitting and interactions
Physics
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container_end_page 4962
container_issue 11
container_start_page 4959
container_title The Journal of chemical physics
container_volume 81
creator CROSSWHITE, H
NEWMAN, D. J
description Fits to spectral energy levels for Ho3+:LaCl3 and Gd3+:LaCl3 establish, for the first time, empirical values of the lanthanide spin-correlated crystal field parameters. The fitted rank 6 parameters are consistent with the superposition model analysis and provide the solution to a long standing problem in the fitted values of the crystal field parameters for trivalent lanthanide ions in LaCl3.
doi_str_mv 10.1063/1.447479
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source AIP Digital Archive
subjects Condensed matter: electronic structure, electrical, magnetic, and optical properties
Crystal and ligand fields
Electron states
Exact sciences and technology
Level splitting and interactions
Physics
title Spin-correlated crystal field parameters for lanthanide ions substituted into LaCl3
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