An ion beam study of reactive scattering of halide ions by methyl halides
Measurements of electron detachment cross sections, reactive charge transfer, and differential elastic and inelastic scattering cross sections for Cl−, Br−, and I− ions on CH3I, CH3Br, and CH3Cl targets are reported. The energy range for the experiments is from 3 to 150 eV. Of the very large number...
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| Veröffentlicht in: | J. Chem. Phys.; (United States) 1984-02, Vol.80 (3), p.1108-1115 |
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| container_end_page | 1115 |
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| container_issue | 3 |
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| container_title | J. Chem. Phys.; (United States) |
| container_volume | 80 |
| creator | WHITE, N. R SCOTT, D HUQ, M. S DOVERSPIKE, L. D CHAMPION, R. L |
| description | Measurements of electron detachment cross sections, reactive charge transfer, and differential elastic and inelastic scattering cross sections for Cl−, Br−, and I− ions on CH3I, CH3Br, and CH3Cl targets are reported. The energy range for the experiments is from 3 to 150 eV. Of the very large number of reaction channels open, it appears that most make significant contributions to the total cross section for sufficiently high projectile energies. The SN2 reaction, which may be dominant at lower energies, was not observed and is probably not significant above the lowest energies in this study. Surviving primary ions exhibit a broad spectrum of inelastic loss, suggesting target breakup. |
| doi_str_mv | 10.1063/1.446839 |
| format | Article |
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R ; SCOTT, D ; HUQ, M. S ; DOVERSPIKE, L. D ; CHAMPION, R. L</creator><creatorcontrib>WHITE, N. R ; SCOTT, D ; HUQ, M. S ; DOVERSPIKE, L. D ; CHAMPION, R. L ; Department of Physics, The College of William and Mary, Williamsburg, Virginia 23185</creatorcontrib><description>Measurements of electron detachment cross sections, reactive charge transfer, and differential elastic and inelastic scattering cross sections for Cl−, Br−, and I− ions on CH3I, CH3Br, and CH3Cl targets are reported. The energy range for the experiments is from 3 to 150 eV. Of the very large number of reaction channels open, it appears that most make significant contributions to the total cross section for sufficiently high projectile energies. The SN2 reaction, which may be dominant at lower energies, was not observed and is probably not significant above the lowest energies in this study. Surviving primary ions exhibit a broad spectrum of inelastic loss, suggesting target breakup.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.446839</identifier><identifier>CODEN: JCPSA6</identifier><language>eng</language><publisher>Woodbury, NY: American Institute of Physics</publisher><subject>640304 - Atomic, Molecular & Chemical Physics- Collision Phenomena ; ANIONS ; ATOMIC AND MOLECULAR PHYSICS ; ATOMIC IONS ; BEAMS ; BROMINATED ALIPHATIC HYDROCARBONS ; BROMINE IONS ; CHARGED PARTICLES ; CHEMICAL REACTIONS ; Chemistry ; CHLORINATED ALIPHATIC HYDROCARBONS ; CHLORINE IONS ; COLLISIONS ; ELECTRON DETACHMENT ; ENERGY RANGE ; EV RANGE ; EV RANGE 01-10 ; EV RANGE 10-100 ; Exact sciences and technology ; HALOGENATED ALIPHATIC HYDROCARBONS ; IODINATED ALIPHATIC HYDROCARBONS ; IODINE IONS ; ION BEAMS ; ION COLLISIONS ; ION-MOLECULE COLLISIONS ; IONS ; Kinetics and mechanisms ; METHYL BROMIDE ; METHYL CHLORIDE ; METHYL IODIDE ; MOLECULE COLLISIONS ; ORGANIC BROMINE COMPOUNDS ; Organic chemistry ; ORGANIC CHLORINE COMPOUNDS ; ORGANIC COMPOUNDS ; ORGANIC HALOGEN COMPOUNDS ; ORGANIC IODINE COMPOUNDS ; Reactivity and mechanisms</subject><ispartof>J. Chem. Phys.; (United States), 1984-02, Vol.80 (3), p.1108-1115</ispartof><rights>1984 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c283t-41701f8f1fe2fc67c787190c24f39aec42ade2a328e0679638c995917cca4f853</citedby><cites>FETCH-LOGICAL-c283t-41701f8f1fe2fc67c787190c24f39aec42ade2a328e0679638c995917cca4f853</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=9708115$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/5375775$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>WHITE, N. R</creatorcontrib><creatorcontrib>SCOTT, D</creatorcontrib><creatorcontrib>HUQ, M. S</creatorcontrib><creatorcontrib>DOVERSPIKE, L. D</creatorcontrib><creatorcontrib>CHAMPION, R. L</creatorcontrib><creatorcontrib>Department of Physics, The College of William and Mary, Williamsburg, Virginia 23185</creatorcontrib><title>An ion beam study of reactive scattering of halide ions by methyl halides</title><title>J. Chem. Phys.; (United States)</title><description>Measurements of electron detachment cross sections, reactive charge transfer, and differential elastic and inelastic scattering cross sections for Cl−, Br−, and I− ions on CH3I, CH3Br, and CH3Cl targets are reported. The energy range for the experiments is from 3 to 150 eV. Of the very large number of reaction channels open, it appears that most make significant contributions to the total cross section for sufficiently high projectile energies. The SN2 reaction, which may be dominant at lower energies, was not observed and is probably not significant above the lowest energies in this study. Surviving primary ions exhibit a broad spectrum of inelastic loss, suggesting target breakup.</description><subject>640304 - Atomic, Molecular & Chemical Physics- Collision Phenomena</subject><subject>ANIONS</subject><subject>ATOMIC AND MOLECULAR PHYSICS</subject><subject>ATOMIC IONS</subject><subject>BEAMS</subject><subject>BROMINATED ALIPHATIC HYDROCARBONS</subject><subject>BROMINE IONS</subject><subject>CHARGED PARTICLES</subject><subject>CHEMICAL REACTIONS</subject><subject>Chemistry</subject><subject>CHLORINATED ALIPHATIC HYDROCARBONS</subject><subject>CHLORINE IONS</subject><subject>COLLISIONS</subject><subject>ELECTRON DETACHMENT</subject><subject>ENERGY RANGE</subject><subject>EV RANGE</subject><subject>EV RANGE 01-10</subject><subject>EV RANGE 10-100</subject><subject>Exact sciences and technology</subject><subject>HALOGENATED ALIPHATIC HYDROCARBONS</subject><subject>IODINATED ALIPHATIC HYDROCARBONS</subject><subject>IODINE IONS</subject><subject>ION BEAMS</subject><subject>ION COLLISIONS</subject><subject>ION-MOLECULE COLLISIONS</subject><subject>IONS</subject><subject>Kinetics and mechanisms</subject><subject>METHYL BROMIDE</subject><subject>METHYL CHLORIDE</subject><subject>METHYL IODIDE</subject><subject>MOLECULE COLLISIONS</subject><subject>ORGANIC BROMINE COMPOUNDS</subject><subject>Organic chemistry</subject><subject>ORGANIC CHLORINE COMPOUNDS</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC HALOGEN COMPOUNDS</subject><subject>ORGANIC IODINE COMPOUNDS</subject><subject>Reactivity and mechanisms</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1984</creationdate><recordtype>article</recordtype><recordid>eNo90EtLAzEUBeAgCtYq-BOCuHAz9d5kJo9lKT4KBTe6HtLbxEamM2UShfn3dhhxdeHwceAexm4RFghKPuKiLJWR9ozNEIwttLJwzmYAAgurQF2yq5S-AAC1KGdsvWx57Fq-9e7AU_7eDbwLvPeOcvzxPJHL2fex_RzjvWvizo8-8e3ADz7vh-YvTdfsIrgm-Zu_O2cfz0_vq9di8_ayXi03BQkjc1GiBgwmYPAikNKkjUYLJMogrfNUCrfzwklhPChtlTRkbWVRE7kymErO2d3U26Uc60Qxe9pT17aecl1JXWk9oocJUd-l1PtQH_t4cP1QI9TjTjXW004nej_Rozt924TetRTTv7caDGIlfwHZc2Vk</recordid><startdate>19840201</startdate><enddate>19840201</enddate><creator>WHITE, N. R</creator><creator>SCOTT, D</creator><creator>HUQ, M. S</creator><creator>DOVERSPIKE, L. D</creator><creator>CHAMPION, R. L</creator><general>American Institute of Physics</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19840201</creationdate><title>An ion beam study of reactive scattering of halide ions by methyl halides</title><author>WHITE, N. R ; SCOTT, D ; HUQ, M. S ; DOVERSPIKE, L. D ; CHAMPION, R. L</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c283t-41701f8f1fe2fc67c787190c24f39aec42ade2a328e0679638c995917cca4f853</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1984</creationdate><topic>640304 - Atomic, Molecular & Chemical Physics- Collision Phenomena</topic><topic>ANIONS</topic><topic>ATOMIC AND MOLECULAR PHYSICS</topic><topic>ATOMIC IONS</topic><topic>BEAMS</topic><topic>BROMINATED ALIPHATIC HYDROCARBONS</topic><topic>BROMINE IONS</topic><topic>CHARGED PARTICLES</topic><topic>CHEMICAL REACTIONS</topic><topic>Chemistry</topic><topic>CHLORINATED ALIPHATIC HYDROCARBONS</topic><topic>CHLORINE IONS</topic><topic>COLLISIONS</topic><topic>ELECTRON DETACHMENT</topic><topic>ENERGY RANGE</topic><topic>EV RANGE</topic><topic>EV RANGE 01-10</topic><topic>EV RANGE 10-100</topic><topic>Exact sciences and technology</topic><topic>HALOGENATED ALIPHATIC HYDROCARBONS</topic><topic>IODINATED ALIPHATIC HYDROCARBONS</topic><topic>IODINE IONS</topic><topic>ION BEAMS</topic><topic>ION COLLISIONS</topic><topic>ION-MOLECULE COLLISIONS</topic><topic>IONS</topic><topic>Kinetics and mechanisms</topic><topic>METHYL BROMIDE</topic><topic>METHYL CHLORIDE</topic><topic>METHYL IODIDE</topic><topic>MOLECULE COLLISIONS</topic><topic>ORGANIC BROMINE COMPOUNDS</topic><topic>Organic chemistry</topic><topic>ORGANIC CHLORINE COMPOUNDS</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC HALOGEN COMPOUNDS</topic><topic>ORGANIC IODINE COMPOUNDS</topic><topic>Reactivity and mechanisms</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>WHITE, N. R</creatorcontrib><creatorcontrib>SCOTT, D</creatorcontrib><creatorcontrib>HUQ, M. S</creatorcontrib><creatorcontrib>DOVERSPIKE, L. D</creatorcontrib><creatorcontrib>CHAMPION, R. L</creatorcontrib><creatorcontrib>Department of Physics, The College of William and Mary, Williamsburg, Virginia 23185</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Chem. Phys.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>WHITE, N. R</au><au>SCOTT, D</au><au>HUQ, M. S</au><au>DOVERSPIKE, L. D</au><au>CHAMPION, R. L</au><aucorp>Department of Physics, The College of William and Mary, Williamsburg, Virginia 23185</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An ion beam study of reactive scattering of halide ions by methyl halides</atitle><jtitle>J. Chem. Phys.; (United States)</jtitle><date>1984-02-01</date><risdate>1984</risdate><volume>80</volume><issue>3</issue><spage>1108</spage><epage>1115</epage><pages>1108-1115</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><coden>JCPSA6</coden><abstract>Measurements of electron detachment cross sections, reactive charge transfer, and differential elastic and inelastic scattering cross sections for Cl−, Br−, and I− ions on CH3I, CH3Br, and CH3Cl targets are reported. The energy range for the experiments is from 3 to 150 eV. Of the very large number of reaction channels open, it appears that most make significant contributions to the total cross section for sufficiently high projectile energies. The SN2 reaction, which may be dominant at lower energies, was not observed and is probably not significant above the lowest energies in this study. Surviving primary ions exhibit a broad spectrum of inelastic loss, suggesting target breakup.</abstract><cop>Woodbury, NY</cop><pub>American Institute of Physics</pub><doi>10.1063/1.446839</doi><tpages>8</tpages></addata></record> |
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| identifier | ISSN: 0021-9606 |
| ispartof | J. Chem. Phys.; (United States), 1984-02, Vol.80 (3), p.1108-1115 |
| issn | 0021-9606 1089-7690 |
| language | eng |
| recordid | cdi_crossref_primary_10_1063_1_446839 |
| source | AIP Digital Archive |
| subjects | 640304 - Atomic, Molecular & Chemical Physics- Collision Phenomena ANIONS ATOMIC AND MOLECULAR PHYSICS ATOMIC IONS BEAMS BROMINATED ALIPHATIC HYDROCARBONS BROMINE IONS CHARGED PARTICLES CHEMICAL REACTIONS Chemistry CHLORINATED ALIPHATIC HYDROCARBONS CHLORINE IONS COLLISIONS ELECTRON DETACHMENT ENERGY RANGE EV RANGE EV RANGE 01-10 EV RANGE 10-100 Exact sciences and technology HALOGENATED ALIPHATIC HYDROCARBONS IODINATED ALIPHATIC HYDROCARBONS IODINE IONS ION BEAMS ION COLLISIONS ION-MOLECULE COLLISIONS IONS Kinetics and mechanisms METHYL BROMIDE METHYL CHLORIDE METHYL IODIDE MOLECULE COLLISIONS ORGANIC BROMINE COMPOUNDS Organic chemistry ORGANIC CHLORINE COMPOUNDS ORGANIC COMPOUNDS ORGANIC HALOGEN COMPOUNDS ORGANIC IODINE COMPOUNDS Reactivity and mechanisms |
| title | An ion beam study of reactive scattering of halide ions by methyl halides |
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