Hypersonic relaxation studies of molten zinc chloride
Brillouin spectroscopy has been used to study the frequency and temperature dependence of sonic waves in molten ZnCl2. The hypersonic velocity has been determined for two different scattering angles, 90.1° and 140.2°, and in the temperature range 294–741 °C, where a relaxation process was revealed....
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Veröffentlicht in: | The Journal of chemical physics 1984-05, Vol.80 (10), p.4788-4793 |
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description | Brillouin spectroscopy has been used to study the frequency and temperature dependence of sonic waves in molten ZnCl2. The hypersonic velocity has been determined for two different scattering angles, 90.1° and 140.2°, and in the temperature range 294–741 °C, where a relaxation process was revealed. The sound absorption has been studied at temperatures lower and higher than those corresponding to the absorption peak. Shear and structural relaxations were both present with the same single relaxation time within experimental uncertainty. The temperature dependence of the longitudinal relaxation time was an Arrhenius type relation. |
doi_str_mv | 10.1063/1.446552 |
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E. G</creatorcontrib><title>Hypersonic relaxation studies of molten zinc chloride</title><title>The Journal of chemical physics</title><description>Brillouin spectroscopy has been used to study the frequency and temperature dependence of sonic waves in molten ZnCl2. The hypersonic velocity has been determined for two different scattering angles, 90.1° and 140.2°, and in the temperature range 294–741 °C, where a relaxation process was revealed. The sound absorption has been studied at temperatures lower and higher than those corresponding to the absorption peak. Shear and structural relaxations were both present with the same single relaxation time within experimental uncertainty. The temperature dependence of the longitudinal relaxation time was an Arrhenius type relation.</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>Mechanical and acoustical properties of condensed matter</subject><subject>Physics</subject><subject>Ultrasonic relaxation</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1984</creationdate><recordtype>article</recordtype><recordid>eNo9z01LxDAUheEgCtZR8Cdk4cJNx3vz0SRLGdQRBtzouqRpgpFOU5IKjr_ekYqrs3k48BJyjbBGaPgdroVopGQnpELQplaNgVNSATCsTQPNObko5QMAUDFREbk9TD6XNEZHsx_sl51jGmmZP_voC02B7tMw-5F-x9FR9z6kHHt_Sc6CHYq_-tsVeXt8eN1s693L0_Pmflc7zmCueyGY0VJ24CUq9Nwr0ExaLr3xQiuLSgvXaVQSRM9lwMC6wFTPj8J1gq_I7fLrciol-9BOOe5tPrQI7W9ui-2Se6Q3C51scXYI2Y4uln-vtUZUhv8Af2dSuA</recordid><startdate>19840515</startdate><enddate>19840515</enddate><creator>KNAPE, H. E. G</creator><general>American Institute of Physics</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19840515</creationdate><title>Hypersonic relaxation studies of molten zinc chloride</title><author>KNAPE, H. E. G</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c320t-d4429855b0e5171e3e70825a35e9e487a1784cb817504d35f1f2bf27d335ecb43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1984</creationdate><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Mechanical and acoustical properties of condensed matter</topic><topic>Physics</topic><topic>Ultrasonic relaxation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>KNAPE, H. E. G</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>KNAPE, H. E. G</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hypersonic relaxation studies of molten zinc chloride</atitle><jtitle>The Journal of chemical physics</jtitle><date>1984-05-15</date><risdate>1984</risdate><volume>80</volume><issue>10</issue><spage>4788</spage><epage>4793</epage><pages>4788-4793</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><coden>JCPSA6</coden><abstract>Brillouin spectroscopy has been used to study the frequency and temperature dependence of sonic waves in molten ZnCl2. The hypersonic velocity has been determined for two different scattering angles, 90.1° and 140.2°, and in the temperature range 294–741 °C, where a relaxation process was revealed. The sound absorption has been studied at temperatures lower and higher than those corresponding to the absorption peak. Shear and structural relaxations were both present with the same single relaxation time within experimental uncertainty. The temperature dependence of the longitudinal relaxation time was an Arrhenius type relation.</abstract><cop>Woodbury, NY</cop><pub>American Institute of Physics</pub><doi>10.1063/1.446552</doi><tpages>6</tpages></addata></record> |
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subjects | Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Mechanical and acoustical properties of condensed matter Physics Ultrasonic relaxation |
title | Hypersonic relaxation studies of molten zinc chloride |
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