Vibrational excitation of the allene–fluorine reaction in cryogenic matrices: Possible mode selectivity

The infrared induced reaction of allene (C3H4) and fluorine in N2, Ar, Kr, and Xe matrices at 12 K has been studied. The reaction is promoted by the selective vibrational excitation of C3H4 ⋅ F2 reactive pairs and the course of the reaction followed by infrared spectroscopy. Four products are detect...

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Veröffentlicht in:The Journal of chemical physics 1983-01, Vol.78 (11), p.6780-6792
Hauptverfasser: Knudsen, Arne K., Pimentel, George C.
Format: Artikel
Sprache:eng
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