Effect of rotational temperature on the glory undulations in the atom–diatom total collision cross section

The effect of the rotational temperature of the O2 molecules on the glory structure in the total collision cross section has been observed for O2–Ar and O2–Kr systems. For O2–Kr the effect has been well characterized by the comparison of the cross sections with those for Ar–Kr system. The cross sect...

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Veröffentlicht in:J. Chem. Phys.; (United States) 1981-07, Vol.75 (2), p.1042-1043
Hauptverfasser: Pirani, F., Vecchiocattivi, F., van den Biesen, J. J. H., van den Meijdenberg, C. J. N.
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container_title J. Chem. Phys.; (United States)
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creator Pirani, F.
Vecchiocattivi, F.
van den Biesen, J. J. H.
van den Meijdenberg, C. J. N.
description The effect of the rotational temperature of the O2 molecules on the glory structure in the total collision cross section has been observed for O2–Ar and O2–Kr systems. For O2–Kr the effect has been well characterized by the comparison of the cross sections with those for Ar–Kr system. The cross sections with O2 molecules at a rotational temperture of ∼900 K are close to the atom–atom results, while the cross sections with O2 at low rotational temperature of 10–150 K show a modification of the glory structure due to the anisotropy of the interaction.(AIP)
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N.</creatorcontrib><creatorcontrib>Dipartimento di Chimica dell'Universita, 06100 Perugia, Italy</creatorcontrib><title>Effect of rotational temperature on the glory undulations in the atom–diatom total collision cross section</title><title>J. Chem. Phys.; (United States)</title><description>The effect of the rotational temperature of the O2 molecules on the glory structure in the total collision cross section has been observed for O2–Ar and O2–Kr systems. For O2–Kr the effect has been well characterized by the comparison of the cross sections with those for Ar–Kr system. 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ispartof J. Chem. Phys.; (United States), 1981-07, Vol.75 (2), p.1042-1043
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subjects 640304 - Atomic, Molecular & Chemical Physics- Collision Phenomena
ARGON
ATOM COLLISIONS
ATOM-MOLECULE COLLISIONS
ATOMIC AND MOLECULAR PHYSICS
COLLISIONS
CROSS SECTIONS
ELEMENTS
ENERGY LEVELS
EXCITED STATES
FLUIDS
GASES
KRYPTON
MOLECULE COLLISIONS
MOLECULES
NONMETALS
OXYGEN
RARE GASES
ROTATIONAL STATES
TEMPERATURE DEPENDENCE
title Effect of rotational temperature on the glory undulations in the atom–diatom total collision cross section
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