Direct absorption measurement of the spin–orbit splitting and 2 P 1/2 radiative lifetime in atomic fluorine (2 p 5)

Direct absorption measurement of the spin–orbit splitting and 2 P 1/2 radiative lifetime in atomic fluorine (2 p 5)

We report the first direct measurement of the fluorine atom ground state fine structure transition. The transition was measured by diode laser absorption spectroscopy. The position of the (J=3/2, F=2)→(J=1/2, F=1) absorption line was measured with high precision relative to a pure rotational transit...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:The Journal of chemical physics 1980-06, Vol.72 (12), p.6637-6641
Hauptverfasser: Stanton, Alan C., Kolb, Charles E.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 6641
container_issue 12
container_start_page 6637
container_title The Journal of chemical physics
container_volume 72
creator Stanton, Alan C.
Kolb, Charles E.
description We report the first direct measurement of the fluorine atom ground state fine structure transition. The transition was measured by diode laser absorption spectroscopy. The position of the (J=3/2, F=2)→(J=1/2, F=1) absorption line was measured with high precision relative to a pure rotational transition in H2O, establishing the fine structure energy splitting as 404.082 cm−1 ±0.025. The measured transition probability for the hyperfine component is 1.26×10−3 s−1 (±25%), yielding a radiative lifetime of 660 s for the 2P1/2 fine structure level.
doi_str_mv 10.1063/1.439122
format Article
fullrecord <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1063_1_439122</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1063_1_439122</sourcerecordid><originalsourceid>FETCH-LOGICAL-c722-39cd6ed9508024c8901747b22ef98e43021b3e0c0f9582cca2486151428dc2783</originalsourceid><addsrcrecordid>eNotkM1KAzEUhYMoWKvgI9xlXUx7c-cvWUq1KhR00f2QydzRyPyRpII738E39Ems1NXhbA7f-YS4lriUWKQrucxSLYlOxEyi0klZaDwVM0SSiS6wOBcXIbwjoiwpm4n9nfNsI5g6jH6KbhygZxP2nnseIowtxDeGMLnh5-t79LWLh9K5GN3wCmZogOAF5IrAm8aZ6D4YOtdydD2DG8DEsXcW2m4_ejcwLAgmyG8uxVlrusBX_zkXu839bv2YbJ8fnta328SWREmqbVNwo3NUSJlV-sCclTURt1pxlh4u1SmjxVbniqw1lKlC5jIj1VgqVToXi-Os9WMInttq8q43_rOSWP3ZqmR1tJX-AsIsW4M</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Direct absorption measurement of the spin–orbit splitting and 2 P 1/2 radiative lifetime in atomic fluorine (2 p 5)</title><source>AIP Digital Archive</source><creator>Stanton, Alan C. ; Kolb, Charles E.</creator><creatorcontrib>Stanton, Alan C. ; Kolb, Charles E.</creatorcontrib><description>We report the first direct measurement of the fluorine atom ground state fine structure transition. The transition was measured by diode laser absorption spectroscopy. The position of the (J=3/2, F=2)→(J=1/2, F=1) absorption line was measured with high precision relative to a pure rotational transition in H2O, establishing the fine structure energy splitting as 404.082 cm−1 ±0.025. The measured transition probability for the hyperfine component is 1.26×10−3 s−1 (±25%), yielding a radiative lifetime of 660 s for the 2P1/2 fine structure level.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.439122</identifier><language>eng</language><ispartof>The Journal of chemical physics, 1980-06, Vol.72 (12), p.6637-6641</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c722-39cd6ed9508024c8901747b22ef98e43021b3e0c0f9582cca2486151428dc2783</citedby><cites>FETCH-LOGICAL-c722-39cd6ed9508024c8901747b22ef98e43021b3e0c0f9582cca2486151428dc2783</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Stanton, Alan C.</creatorcontrib><creatorcontrib>Kolb, Charles E.</creatorcontrib><title>Direct absorption measurement of the spin–orbit splitting and 2 P 1/2 radiative lifetime in atomic fluorine (2 p 5)</title><title>The Journal of chemical physics</title><description>We report the first direct measurement of the fluorine atom ground state fine structure transition. The transition was measured by diode laser absorption spectroscopy. The position of the (J=3/2, F=2)→(J=1/2, F=1) absorption line was measured with high precision relative to a pure rotational transition in H2O, establishing the fine structure energy splitting as 404.082 cm−1 ±0.025. The measured transition probability for the hyperfine component is 1.26×10−3 s−1 (±25%), yielding a radiative lifetime of 660 s for the 2P1/2 fine structure level.</description><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1980</creationdate><recordtype>article</recordtype><recordid>eNotkM1KAzEUhYMoWKvgI9xlXUx7c-cvWUq1KhR00f2QydzRyPyRpII738E39Ems1NXhbA7f-YS4lriUWKQrucxSLYlOxEyi0klZaDwVM0SSiS6wOBcXIbwjoiwpm4n9nfNsI5g6jH6KbhygZxP2nnseIowtxDeGMLnh5-t79LWLh9K5GN3wCmZogOAF5IrAm8aZ6D4YOtdydD2DG8DEsXcW2m4_ejcwLAgmyG8uxVlrusBX_zkXu839bv2YbJ8fnta328SWREmqbVNwo3NUSJlV-sCclTURt1pxlh4u1SmjxVbniqw1lKlC5jIj1VgqVToXi-Os9WMInttq8q43_rOSWP3ZqmR1tJX-AsIsW4M</recordid><startdate>19800615</startdate><enddate>19800615</enddate><creator>Stanton, Alan C.</creator><creator>Kolb, Charles E.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19800615</creationdate><title>Direct absorption measurement of the spin–orbit splitting and 2 P 1/2 radiative lifetime in atomic fluorine (2 p 5)</title><author>Stanton, Alan C. ; Kolb, Charles E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c722-39cd6ed9508024c8901747b22ef98e43021b3e0c0f9582cca2486151428dc2783</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1980</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Stanton, Alan C.</creatorcontrib><creatorcontrib>Kolb, Charles E.</creatorcontrib><collection>CrossRef</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Stanton, Alan C.</au><au>Kolb, Charles E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Direct absorption measurement of the spin–orbit splitting and 2 P 1/2 radiative lifetime in atomic fluorine (2 p 5)</atitle><jtitle>The Journal of chemical physics</jtitle><date>1980-06-15</date><risdate>1980</risdate><volume>72</volume><issue>12</issue><spage>6637</spage><epage>6641</epage><pages>6637-6641</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>We report the first direct measurement of the fluorine atom ground state fine structure transition. The transition was measured by diode laser absorption spectroscopy. The position of the (J=3/2, F=2)→(J=1/2, F=1) absorption line was measured with high precision relative to a pure rotational transition in H2O, establishing the fine structure energy splitting as 404.082 cm−1 ±0.025. The measured transition probability for the hyperfine component is 1.26×10−3 s−1 (±25%), yielding a radiative lifetime of 660 s for the 2P1/2 fine structure level.</abstract><doi>10.1063/1.439122</doi><tpages>5</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0021-9606
ispartof The Journal of chemical physics, 1980-06, Vol.72 (12), p.6637-6641
issn 0021-9606
1089-7690
language eng
recordid cdi_crossref_primary_10_1063_1_439122
source AIP Digital Archive
title Direct absorption measurement of the spin–orbit splitting and 2 P 1/2 radiative lifetime in atomic fluorine (2 p 5)
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-10T10%3A45%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Direct%20absorption%20measurement%20of%20the%20spin%E2%80%93orbit%20splitting%20and%202%20P%201/2%20radiative%20lifetime%20in%20atomic%20fluorine%20(2%20p%205)&rft.jtitle=The%20Journal%20of%20chemical%20physics&rft.au=Stanton,%20Alan%20C.&rft.date=1980-06-15&rft.volume=72&rft.issue=12&rft.spage=6637&rft.epage=6641&rft.pages=6637-6641&rft.issn=0021-9606&rft.eissn=1089-7690&rft_id=info:doi/10.1063/1.439122&rft_dat=%3Ccrossref%3E10_1063_1_439122%3C/crossref%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true