Inference of vibrational anharmonicity in hot SF6: An electron diffraction study

In an investigation of gaseous SF6 at temperatures ranging from 298 to almost 1000 K, the observed thermal expansion of the mean bond length as a function of the mean-square amplitude of vibration was found to be much too large to be accounted for by the commonly invoked model of Morse anharmonicity...

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Veröffentlicht in:The Journal of chemical physics 1979-05, Vol.70 (10), p.4585-4586
Hauptverfasser: Bartell, L. S., Doun, S. K., Goates, S. R.
Format: Artikel
Sprache:eng
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