Inference of vibrational anharmonicity in hot SF6: An electron diffraction study
In an investigation of gaseous SF6 at temperatures ranging from 298 to almost 1000 K, the observed thermal expansion of the mean bond length as a function of the mean-square amplitude of vibration was found to be much too large to be accounted for by the commonly invoked model of Morse anharmonicity...
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Veröffentlicht in: | The Journal of chemical physics 1979-05, Vol.70 (10), p.4585-4586 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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