The Raman spectrum of NF3: Coriolis coupling and transition dipole interaction in the liquid

First order Coriolis coupling in an e-symmetry mode of a symmetric top and its consequences on the associated Raman line in the liquid are investigated for classical rotations and a classical harmonic vibration. Except for quantum asymmetries, the overall features of the Raman line are reproduced. The second and fourth classical moments of the e-symmetry Raman line are given together with an expression of the linewidth for Debye diffusion. The relevant autocorrelation function