The Mössbauer isomer shift in iron (III) sulfate
The Mössbauer spectra of the rhombohedral and monoclinic modifications of Fe(III) sulfate have been measured. The isomer shift is 0.496 mm s−1 relative to α-Fe for both modifications and the quadrupole splittings are 0.15 and 0.30 mm s−1, respectively. The isomer shift of Fe2(SO4)3 fits on a calibra...
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| Veröffentlicht in: | The Journal of chemical physics 1977-09, Vol.67 (6), p.2825-2829 |
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| container_title | The Journal of chemical physics |
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| creator | Haven, Y. Noftle, R. E. |
| description | The Mössbauer spectra of the rhombohedral and monoclinic modifications of Fe(III) sulfate have been measured. The isomer shift is 0.496 mm s−1 relative to α-Fe for both modifications and the quadrupole splittings are 0.15 and 0.30 mm s−1, respectively. The isomer shift of Fe2(SO4)3 fits on a calibration curve of electron density versus isomer shift proposed by Barrett and Micklitz, and its position is consistent with a high degree of ionic character for the compound. It is proposed to include Fe2(SO4)3 as one of the calibration points for electron density versus isomer shift. |
| doi_str_mv | 10.1063/1.435148 |
| format | Article |
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E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Mössbauer isomer shift in iron (III) sulfate</atitle><jtitle>The Journal of chemical physics</jtitle><date>1977-09-15</date><risdate>1977</risdate><volume>67</volume><issue>6</issue><spage>2825</spage><epage>2829</epage><pages>2825-2829</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>The Mössbauer spectra of the rhombohedral and monoclinic modifications of Fe(III) sulfate have been measured. The isomer shift is 0.496 mm s−1 relative to α-Fe for both modifications and the quadrupole splittings are 0.15 and 0.30 mm s−1, respectively. The isomer shift of Fe2(SO4)3 fits on a calibration curve of electron density versus isomer shift proposed by Barrett and Micklitz, and its position is consistent with a high degree of ionic character for the compound. 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| identifier | ISSN: 0021-9606 |
| ispartof | The Journal of chemical physics, 1977-09, Vol.67 (6), p.2825-2829 |
| issn | 0021-9606 1089-7690 |
| language | eng |
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| source | AIP Digital Archive |
| title | The Mössbauer isomer shift in iron (III) sulfate |
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