Negative ions from phosphorus halides due to cesium charge exchange
An experiment has been conducted in which cesium atoms in the kinetic energy range 2–350 eV collide with phosphorus halides. Parent anions and fragments are formed. Molecular energies are obtained from threshold measurements. The electron affinites for PCl3, POCl3, PBr3, PCl2Br, PBr2Cl, and POCl2 ar...
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| Veröffentlicht in: | J. Chem. Phys.; (United States) 1976-07, Vol.65 (2), p.565-569 |
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| container_title | J. Chem. Phys.; (United States) |
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| creator | Mathur, B. P. Rothe, Erhard W. Tang, S. Y. Reck, Gene P. |
| description | An experiment has been conducted in which cesium atoms in the kinetic energy range 2–350 eV collide with phosphorus halides. Parent anions and fragments are formed. Molecular energies are obtained from threshold measurements. The electron affinites for PCl3, POCl3, PBr3, PCl2Br, PBr2Cl, and POCl2 are found to be 0.8, 1.4, 1.6, 1.5, 1.6, and 3.8 eV, respectively. The P–X bond energies for PCl3, POCl3, and PBr3 are 3.3, 3.5, and 2.6 eV, respectively. |
| doi_str_mv | 10.1063/1.433109 |
| format | Article |
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The P–X bond energies for PCl3, POCl3, and PBr3 are 3.3, 3.5, and 2.6 eV, respectively.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.433109</identifier><language>eng</language><publisher>United States</publisher><subject>640304 - Atomic, Molecular & Chemical Physics- Collision Phenomena ; ALKALI METALS ; ATOM COLLISIONS ; ATOM-MOLECULE COLLISIONS ; ATOMIC AND MOLECULAR PHYSICS ; CESIUM ; CHARGE EXCHANGE ; COLLISIONS ; ELEMENTS ; ENERGY RANGE ; EV RANGE ; EV RANGE 01-10 ; EV RANGE 10-100 ; EV RANGE 100-1000 ; HALIDES ; HALOGEN COMPOUNDS ; IONIZATION ; MASS SPECTRA ; METALS ; MOLECULE COLLISIONS ; PHOSPHORUS COMPOUNDS ; SPECTRA</subject><ispartof>J. Chem. 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Y.</creatorcontrib><creatorcontrib>Reck, Gene P.</creatorcontrib><creatorcontrib>Research Institute for Engineering Sciences and Department of Chemical Engineering, Wayne State University, Detroit, Michigan 48202</creatorcontrib><title>Negative ions from phosphorus halides due to cesium charge exchange</title><title>J. Chem. Phys.; (United States)</title><description>An experiment has been conducted in which cesium atoms in the kinetic energy range 2–350 eV collide with phosphorus halides. Parent anions and fragments are formed. Molecular energies are obtained from threshold measurements. The electron affinites for PCl3, POCl3, PBr3, PCl2Br, PBr2Cl, and POCl2 are found to be 0.8, 1.4, 1.6, 1.5, 1.6, and 3.8 eV, respectively. The P–X bond energies for PCl3, POCl3, and PBr3 are 3.3, 3.5, and 2.6 eV, respectively.</description><subject>640304 - Atomic, Molecular & Chemical Physics- Collision Phenomena</subject><subject>ALKALI METALS</subject><subject>ATOM COLLISIONS</subject><subject>ATOM-MOLECULE COLLISIONS</subject><subject>ATOMIC AND MOLECULAR PHYSICS</subject><subject>CESIUM</subject><subject>CHARGE EXCHANGE</subject><subject>COLLISIONS</subject><subject>ELEMENTS</subject><subject>ENERGY RANGE</subject><subject>EV RANGE</subject><subject>EV RANGE 01-10</subject><subject>EV RANGE 10-100</subject><subject>EV RANGE 100-1000</subject><subject>HALIDES</subject><subject>HALOGEN COMPOUNDS</subject><subject>IONIZATION</subject><subject>MASS SPECTRA</subject><subject>METALS</subject><subject>MOLECULE COLLISIONS</subject><subject>PHOSPHORUS COMPOUNDS</subject><subject>SPECTRA</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1976</creationdate><recordtype>article</recordtype><recordid>eNotkE1LAzEURYMoWKvgTwiu3Ex9SSaZyVKKX1B0o-uQvnnpRNpJSWZE_72VurjcuzjcxWHsWsBCgFF3YlErJcCesJmA1laNsXDKZgBSVNaAOWcXpXwCgGhkPWPLV9r4MX4Rj2koPOS04_s-lUPyVHjvt7GjwruJ-Jg4UonTjmPv84Y4fR_GsKFLdhb8ttDVf8_Zx-PD-_K5Wr09vSzvVxVKLcdKdYo6CKHxWhjbSq2kWqPxXWO8pYDkNeK6rr1WYFvfSaN0g0pJDFYFRDVnN8ffVMboCsaRsMc0DISja0QrtGkP0O0RwpxKyRTcPsedzz9OgPsz5IQ7GlK_3htYKA</recordid><startdate>19760715</startdate><enddate>19760715</enddate><creator>Mathur, B. P.</creator><creator>Rothe, Erhard W.</creator><creator>Tang, S. Y.</creator><creator>Reck, Gene P.</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19760715</creationdate><title>Negative ions from phosphorus halides due to cesium charge exchange</title><author>Mathur, B. P. ; Rothe, Erhard W. ; Tang, S. Y. ; Reck, Gene P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c252t-3d3ed0ff7a5169825323bc6ad76a9efcea5ccb44a53098ad26357c332cf93fcc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1976</creationdate><topic>640304 - Atomic, Molecular & Chemical Physics- Collision Phenomena</topic><topic>ALKALI METALS</topic><topic>ATOM COLLISIONS</topic><topic>ATOM-MOLECULE COLLISIONS</topic><topic>ATOMIC AND MOLECULAR PHYSICS</topic><topic>CESIUM</topic><topic>CHARGE EXCHANGE</topic><topic>COLLISIONS</topic><topic>ELEMENTS</topic><topic>ENERGY RANGE</topic><topic>EV RANGE</topic><topic>EV RANGE 01-10</topic><topic>EV RANGE 10-100</topic><topic>EV RANGE 100-1000</topic><topic>HALIDES</topic><topic>HALOGEN COMPOUNDS</topic><topic>IONIZATION</topic><topic>MASS SPECTRA</topic><topic>METALS</topic><topic>MOLECULE COLLISIONS</topic><topic>PHOSPHORUS COMPOUNDS</topic><topic>SPECTRA</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mathur, B. P.</creatorcontrib><creatorcontrib>Rothe, Erhard W.</creatorcontrib><creatorcontrib>Tang, S. Y.</creatorcontrib><creatorcontrib>Reck, Gene P.</creatorcontrib><creatorcontrib>Research Institute for Engineering Sciences and Department of Chemical Engineering, Wayne State University, Detroit, Michigan 48202</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Chem. Phys.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mathur, B. P.</au><au>Rothe, Erhard W.</au><au>Tang, S. Y.</au><au>Reck, Gene P.</au><aucorp>Research Institute for Engineering Sciences and Department of Chemical Engineering, Wayne State University, Detroit, Michigan 48202</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Negative ions from phosphorus halides due to cesium charge exchange</atitle><jtitle>J. Chem. Phys.; (United States)</jtitle><date>1976-07-15</date><risdate>1976</risdate><volume>65</volume><issue>2</issue><spage>565</spage><epage>569</epage><pages>565-569</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>An experiment has been conducted in which cesium atoms in the kinetic energy range 2–350 eV collide with phosphorus halides. Parent anions and fragments are formed. Molecular energies are obtained from threshold measurements. The electron affinites for PCl3, POCl3, PBr3, PCl2Br, PBr2Cl, and POCl2 are found to be 0.8, 1.4, 1.6, 1.5, 1.6, and 3.8 eV, respectively. The P–X bond energies for PCl3, POCl3, and PBr3 are 3.3, 3.5, and 2.6 eV, respectively.</abstract><cop>United States</cop><doi>10.1063/1.433109</doi><tpages>5</tpages></addata></record> |
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| identifier | ISSN: 0021-9606 |
| ispartof | J. Chem. Phys.; (United States), 1976-07, Vol.65 (2), p.565-569 |
| issn | 0021-9606 1089-7690 |
| language | eng |
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| source | AIP Digital Archive |
| subjects | 640304 - Atomic, Molecular & Chemical Physics- Collision Phenomena ALKALI METALS ATOM COLLISIONS ATOM-MOLECULE COLLISIONS ATOMIC AND MOLECULAR PHYSICS CESIUM CHARGE EXCHANGE COLLISIONS ELEMENTS ENERGY RANGE EV RANGE EV RANGE 01-10 EV RANGE 10-100 EV RANGE 100-1000 HALIDES HALOGEN COMPOUNDS IONIZATION MASS SPECTRA METALS MOLECULE COLLISIONS PHOSPHORUS COMPOUNDS SPECTRA |
| title | Negative ions from phosphorus halides due to cesium charge exchange |
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