Potential barrier to internal rotation in methyl fluoroform
The Raman and microwave spectra of CF3CD3 are reported and used to obtain a more accurate determination of the potential barrier to internal rotation. The microwave results give a barrier of 3.2±0.2 kcal/mole, however, this is not in accord with the trends for chlorine or bromine substituted ethanes...
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| Veröffentlicht in: | J. Chem. Phys., v. 63, no. 12, pp. 5498-5499 v. 63, no. 12, pp. 5498-5499, 1975-12, Vol.63 (12), p.5498-5499 |
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| container_end_page | 5499 |
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| container_issue | 12 |
| container_start_page | 5498 |
| container_title | J. Chem. Phys., v. 63, no. 12, pp. 5498-5499 |
| container_volume | 63 |
| creator | Durig, J. R. Bucy, W. E. Wurrey, C. J. |
| description | The Raman and microwave spectra of CF3CD3 are reported and used to obtain a more accurate determination of the potential barrier to internal rotation. The microwave results give a barrier of 3.2±0.2 kcal/mole, however, this is not in accord with the trends for chlorine or bromine substituted ethanes. (AIP) |
| doi_str_mv | 10.1063/1.431289 |
| format | Article |
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J.</creatorcontrib><creatorcontrib>Department of Chemistry, University of South Carolina, Columbia, South Carolina 29208</creatorcontrib><title>Potential barrier to internal rotation in methyl fluoroform</title><title>J. Chem. Phys., v. 63, no. 12, pp. 5498-5499</title><description>The Raman and microwave spectra of CF3CD3 are reported and used to obtain a more accurate determination of the potential barrier to internal rotation. The microwave results give a barrier of 3.2±0.2 kcal/mole, however, this is not in accord with the trends for chlorine or bromine substituted ethanes. (AIP)</description><subject>400302 -Chemistry-Organic Chemistry-Isotope Effects</subject><subject>DEUTERIUM- ISOTOPE EFFECTS</subject><subject>FLUORINATED ALIPHATIC HYDROCARBONS</subject><subject>MICROWAVE SPECTRA</subject><subject>N40220 -Chemistry-Inorganic, Organic, & Physical Chemistry-Isotopic Effects</subject><subject>POTENTIAL ENERGY</subject><subject>RAMAN SPECTRA</subject><subject>ROTATION</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1975</creationdate><recordtype>article</recordtype><recordid>eNotkEtLxDAcxIMoWFfBj1A8een6z6N54EkWX7CgBz2HNE3YSJtIEg_77a3U0zDDj2EYhK4xbDFweoe3jGIi1QlqMEjVCa7gFDUABHeKAz9HF6V8AQAWhDXo_j1VF2swUzuYnIPLbU1tiNXluGQ5VVNDikvSzq4ejlPrp5-Uk095vkRn3kzFXf3rBn0-PX7sXrr92_Pr7mHfWdKT2ilmqDRYABmUULYXgowcCyaIM7SXjnsie0qWRT1Yr0Y5egrcD06NQqnFbNDN2ptKDbrYUJ092BSjs1UzULIXbIFuV8jmVEp2Xn_nMJt81Bj03zMa6_UZ-gtoRVRi</recordid><startdate>19751215</startdate><enddate>19751215</enddate><creator>Durig, J. 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J.</creatorcontrib><creatorcontrib>Department of Chemistry, University of South Carolina, Columbia, South Carolina 29208</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Chem. Phys., v. 63, no. 12, pp. 5498-5499</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Durig, J. R.</au><au>Bucy, W. E.</au><au>Wurrey, C. J.</au><aucorp>Department of Chemistry, University of South Carolina, Columbia, South Carolina 29208</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Potential barrier to internal rotation in methyl fluoroform</atitle><jtitle>J. Chem. 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| fulltext | fulltext |
| identifier | ISSN: 0021-9606 |
| ispartof | J. Chem. Phys., v. 63, no. 12, pp. 5498-5499, 1975-12, Vol.63 (12), p.5498-5499 |
| issn | 0021-9606 1089-7690 |
| language | eng |
| recordid | cdi_crossref_primary_10_1063_1_431289 |
| source | AIP Digital Archive |
| subjects | 400302 -Chemistry-Organic Chemistry-Isotope Effects DEUTERIUM- ISOTOPE EFFECTS FLUORINATED ALIPHATIC HYDROCARBONS MICROWAVE SPECTRA N40220 -Chemistry-Inorganic, Organic, & Physical Chemistry-Isotopic Effects POTENTIAL ENERGY RAMAN SPECTRA ROTATION |
| title | Potential barrier to internal rotation in methyl fluoroform |
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