Site-selective excitation and polarized absorption spectra of Nd3+ in Sr5(PO4)3F and Ca5(PO4)3F
Polarized absorption and fluorescence spectra were analyzed to establish individual energy (Stark) levels of Nd3+ ions in host crystals of Sr5(PO4)3F (SFAP) and Ca5(PO4)3F (FAP). Site-selective excitation and fluorescence facilitated differentiation between Nd3+ ions in emitting sites associated wit...
Gespeichert in:
| Veröffentlicht in: | Journal of applied physics 1996-02, Vol.79 (3), p.1746-1758 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng ; jpn |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1758 |
|---|---|
| container_issue | 3 |
| container_start_page | 1746 |
| container_title | Journal of applied physics |
| container_volume | 79 |
| creator | Gruber, John B. Morrison, Clyde A. Seltzer, Michael D. Wright, Andrew O. Nadler, Melvin P. Allik, Toomas H. Hutchinson, J. Andrew Chai, Bruce H. T. |
| description | Polarized absorption and fluorescence spectra were analyzed to establish individual energy (Stark) levels of Nd3+ ions in host crystals of Sr5(PO4)3F (SFAP) and Ca5(PO4)3F (FAP). Site-selective excitation and fluorescence facilitated differentiation between Nd3+ ions in emitting sites associated with 1.06 μm stimulated emission, and nonemitting Nd3+ ions in other sites. Measurements were made on samples containing different concentrations of Nd3+ at 4 K and higher temperatures. Substitution of Nd3+ for Sr2+ or Ca2+ was accompanied by passive charge compensation during crystal growth. Crystal-field splitting calculations were performed according to site for Stark levels of Nd3+ ions identified spectroscopically. We obtained a final set of crystal-field parameters Bnm for Nd3+ ions in fluorescing sites with a rms. deviation of 7 cm−1 (52 levels in Nd:SFAP) and 8 cm−1 (59 levels in Nd:FAP). For one of the nonemitting sites in Nd:FAP we obtained a final set of Bnm parameters which gave a rms deviation of 6 cm−1 between 46 experimental and calculated levels. |
| doi_str_mv | 10.1063/1.360964 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1063_1_360964</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1063_1_360964</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1388-f93b2ce04fa0f06f3d473c15566b51480db6d8c24c26aa10661c72f26c7848b23</originalsourceid><addsrcrecordid>eNo1UN1KwzAYDaJgnYKPkMuJZH5fkqbppRSnwnDC9DqkaQKRupakiPr0zk2vDofzA-cQcomwQFDiBhdCQa3kESkQdM2qsoRjUgBwZLqu6lNylvMbAKIWdUHMJk6eZd97N8UPT_2ni5Od4rCldtvRcehtit--o7bNQxr3Qh535mTpEOhTJ65p3NJNKufPa3kllvtYY__pOTkJts_-4g9n5HV599I8sNX6_rG5XTGHQmsWatFy50EGCwFUEJ2shMOyVKotUWroWtVpx6XjytrdUIWu4oErV2mpWy5mZH7odWnIOflgxhTfbfoyCOb3GIPmcIz4AfliUkc</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Site-selective excitation and polarized absorption spectra of Nd3+ in Sr5(PO4)3F and Ca5(PO4)3F</title><source>AIP Digital Archive</source><creator>Gruber, John B. ; Morrison, Clyde A. ; Seltzer, Michael D. ; Wright, Andrew O. ; Nadler, Melvin P. ; Allik, Toomas H. ; Hutchinson, J. Andrew ; Chai, Bruce H. T.</creator><creatorcontrib>Gruber, John B. ; Morrison, Clyde A. ; Seltzer, Michael D. ; Wright, Andrew O. ; Nadler, Melvin P. ; Allik, Toomas H. ; Hutchinson, J. Andrew ; Chai, Bruce H. T.</creatorcontrib><description>Polarized absorption and fluorescence spectra were analyzed to establish individual energy (Stark) levels of Nd3+ ions in host crystals of Sr5(PO4)3F (SFAP) and Ca5(PO4)3F (FAP). Site-selective excitation and fluorescence facilitated differentiation between Nd3+ ions in emitting sites associated with 1.06 μm stimulated emission, and nonemitting Nd3+ ions in other sites. Measurements were made on samples containing different concentrations of Nd3+ at 4 K and higher temperatures. Substitution of Nd3+ for Sr2+ or Ca2+ was accompanied by passive charge compensation during crystal growth. Crystal-field splitting calculations were performed according to site for Stark levels of Nd3+ ions identified spectroscopically. We obtained a final set of crystal-field parameters Bnm for Nd3+ ions in fluorescing sites with a rms. deviation of 7 cm−1 (52 levels in Nd:SFAP) and 8 cm−1 (59 levels in Nd:FAP). For one of the nonemitting sites in Nd:FAP we obtained a final set of Bnm parameters which gave a rms deviation of 6 cm−1 between 46 experimental and calculated levels.</description><identifier>ISSN: 0021-8979</identifier><identifier>EISSN: 1089-7550</identifier><identifier>DOI: 10.1063/1.360964</identifier><language>eng ; jpn</language><ispartof>Journal of applied physics, 1996-02, Vol.79 (3), p.1746-1758</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1388-f93b2ce04fa0f06f3d473c15566b51480db6d8c24c26aa10661c72f26c7848b23</citedby><cites>FETCH-LOGICAL-c1388-f93b2ce04fa0f06f3d473c15566b51480db6d8c24c26aa10661c72f26c7848b23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Gruber, John B.</creatorcontrib><creatorcontrib>Morrison, Clyde A.</creatorcontrib><creatorcontrib>Seltzer, Michael D.</creatorcontrib><creatorcontrib>Wright, Andrew O.</creatorcontrib><creatorcontrib>Nadler, Melvin P.</creatorcontrib><creatorcontrib>Allik, Toomas H.</creatorcontrib><creatorcontrib>Hutchinson, J. Andrew</creatorcontrib><creatorcontrib>Chai, Bruce H. T.</creatorcontrib><title>Site-selective excitation and polarized absorption spectra of Nd3+ in Sr5(PO4)3F and Ca5(PO4)3F</title><title>Journal of applied physics</title><description>Polarized absorption and fluorescence spectra were analyzed to establish individual energy (Stark) levels of Nd3+ ions in host crystals of Sr5(PO4)3F (SFAP) and Ca5(PO4)3F (FAP). Site-selective excitation and fluorescence facilitated differentiation between Nd3+ ions in emitting sites associated with 1.06 μm stimulated emission, and nonemitting Nd3+ ions in other sites. Measurements were made on samples containing different concentrations of Nd3+ at 4 K and higher temperatures. Substitution of Nd3+ for Sr2+ or Ca2+ was accompanied by passive charge compensation during crystal growth. Crystal-field splitting calculations were performed according to site for Stark levels of Nd3+ ions identified spectroscopically. We obtained a final set of crystal-field parameters Bnm for Nd3+ ions in fluorescing sites with a rms. deviation of 7 cm−1 (52 levels in Nd:SFAP) and 8 cm−1 (59 levels in Nd:FAP). For one of the nonemitting sites in Nd:FAP we obtained a final set of Bnm parameters which gave a rms deviation of 6 cm−1 between 46 experimental and calculated levels.</description><issn>0021-8979</issn><issn>1089-7550</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1996</creationdate><recordtype>article</recordtype><recordid>eNo1UN1KwzAYDaJgnYKPkMuJZH5fkqbppRSnwnDC9DqkaQKRupakiPr0zk2vDofzA-cQcomwQFDiBhdCQa3kESkQdM2qsoRjUgBwZLqu6lNylvMbAKIWdUHMJk6eZd97N8UPT_2ni5Od4rCldtvRcehtit--o7bNQxr3Qh535mTpEOhTJ65p3NJNKufPa3kllvtYY__pOTkJts_-4g9n5HV599I8sNX6_rG5XTGHQmsWatFy50EGCwFUEJ2shMOyVKotUWroWtVpx6XjytrdUIWu4oErV2mpWy5mZH7odWnIOflgxhTfbfoyCOb3GIPmcIz4AfliUkc</recordid><startdate>19960201</startdate><enddate>19960201</enddate><creator>Gruber, John B.</creator><creator>Morrison, Clyde A.</creator><creator>Seltzer, Michael D.</creator><creator>Wright, Andrew O.</creator><creator>Nadler, Melvin P.</creator><creator>Allik, Toomas H.</creator><creator>Hutchinson, J. Andrew</creator><creator>Chai, Bruce H. T.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19960201</creationdate><title>Site-selective excitation and polarized absorption spectra of Nd3+ in Sr5(PO4)3F and Ca5(PO4)3F</title><author>Gruber, John B. ; Morrison, Clyde A. ; Seltzer, Michael D. ; Wright, Andrew O. ; Nadler, Melvin P. ; Allik, Toomas H. ; Hutchinson, J. Andrew ; Chai, Bruce H. T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1388-f93b2ce04fa0f06f3d473c15566b51480db6d8c24c26aa10661c72f26c7848b23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng ; jpn</language><creationdate>1996</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gruber, John B.</creatorcontrib><creatorcontrib>Morrison, Clyde A.</creatorcontrib><creatorcontrib>Seltzer, Michael D.</creatorcontrib><creatorcontrib>Wright, Andrew O.</creatorcontrib><creatorcontrib>Nadler, Melvin P.</creatorcontrib><creatorcontrib>Allik, Toomas H.</creatorcontrib><creatorcontrib>Hutchinson, J. Andrew</creatorcontrib><creatorcontrib>Chai, Bruce H. T.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of applied physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gruber, John B.</au><au>Morrison, Clyde A.</au><au>Seltzer, Michael D.</au><au>Wright, Andrew O.</au><au>Nadler, Melvin P.</au><au>Allik, Toomas H.</au><au>Hutchinson, J. Andrew</au><au>Chai, Bruce H. T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Site-selective excitation and polarized absorption spectra of Nd3+ in Sr5(PO4)3F and Ca5(PO4)3F</atitle><jtitle>Journal of applied physics</jtitle><date>1996-02-01</date><risdate>1996</risdate><volume>79</volume><issue>3</issue><spage>1746</spage><epage>1758</epage><pages>1746-1758</pages><issn>0021-8979</issn><eissn>1089-7550</eissn><abstract>Polarized absorption and fluorescence spectra were analyzed to establish individual energy (Stark) levels of Nd3+ ions in host crystals of Sr5(PO4)3F (SFAP) and Ca5(PO4)3F (FAP). Site-selective excitation and fluorescence facilitated differentiation between Nd3+ ions in emitting sites associated with 1.06 μm stimulated emission, and nonemitting Nd3+ ions in other sites. Measurements were made on samples containing different concentrations of Nd3+ at 4 K and higher temperatures. Substitution of Nd3+ for Sr2+ or Ca2+ was accompanied by passive charge compensation during crystal growth. Crystal-field splitting calculations were performed according to site for Stark levels of Nd3+ ions identified spectroscopically. We obtained a final set of crystal-field parameters Bnm for Nd3+ ions in fluorescing sites with a rms. deviation of 7 cm−1 (52 levels in Nd:SFAP) and 8 cm−1 (59 levels in Nd:FAP). For one of the nonemitting sites in Nd:FAP we obtained a final set of Bnm parameters which gave a rms deviation of 6 cm−1 between 46 experimental and calculated levels.</abstract><doi>10.1063/1.360964</doi><tpages>13</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-8979 |
| ispartof | Journal of applied physics, 1996-02, Vol.79 (3), p.1746-1758 |
| issn | 0021-8979 1089-7550 |
| language | eng ; jpn |
| recordid | cdi_crossref_primary_10_1063_1_360964 |
| source | AIP Digital Archive |
| title | Site-selective excitation and polarized absorption spectra of Nd3+ in Sr5(PO4)3F and Ca5(PO4)3F |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-27T15%3A17%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Site-selective%20excitation%20and%20polarized%20absorption%20spectra%20of%20Nd3+%20in%20Sr5(PO4)3F%20and%20Ca5(PO4)3F&rft.jtitle=Journal%20of%20applied%20physics&rft.au=Gruber,%20John%20B.&rft.date=1996-02-01&rft.volume=79&rft.issue=3&rft.spage=1746&rft.epage=1758&rft.pages=1746-1758&rft.issn=0021-8979&rft.eissn=1089-7550&rft_id=info:doi/10.1063/1.360964&rft_dat=%3Ccrossref%3E10_1063_1_360964%3C/crossref%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |