Electrochromic vanadium–pentoxide–based films: Structural, electrochemical, and optical properties

Electrochromic vanadium–pentoxide–based films: Structural, electrochemical, and optical properties

Crystalline VO2.5 films were prepared by reactive dc magnetron sputtering followed by annealing posttreatment. Lithium was inserted electrochemically from an electrolyte so that LixVO2.5 (0

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of applied physics 1995-05, Vol.77 (9), p.4655-4666
Hauptverfasser: Talledo, A., Granqvist, C. G.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 4666
container_issue 9
container_start_page 4655
container_title Journal of applied physics
container_volume 77
creator Talledo, A.
Granqvist, C. G.
description Crystalline VO2.5 films were prepared by reactive dc magnetron sputtering followed by annealing posttreatment. Lithium was inserted electrochemically from an electrolyte so that LixVO2.5 (0
doi_str_mv 10.1063/1.359433
format Article
fullrecord <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1063_1_359433</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1063_1_359433</sourcerecordid><originalsourceid>FETCH-LOGICAL-c291t-7aa8148528efff7fca4f85366332e7eb17dbc3b4fa3c422e1276e10a4e2a40553</originalsourceid><addsrcrecordid>eNo1kMtKxDAUhoMoOI6Cj9ClCzvm5NKk7mQYLzDgQl2X0_QEK-20JKnoznfwDX0SZxhd_Rf4_sXP2DnwBfBCXsFC6lJJecBmwG2ZG635IZtxLiC3pSmP2UmMb5wDWFnOmF915FIY3GsY-tZl77jBpp36n6_vkTZp-Ggb2voaIzWZb7s-XmdPKUwuTQG7y4z-cdrSuwI3TTaMaReyMQwjhdRSPGVHHrtIZ386Zy-3q-flfb5-vHtY3qxzJ0pIuUG0oKwWlrz3xjtU3mpZFFIKMlSDaWona-VROiUEgTAFAUdFAhXXWs7ZxX7XhSHGQL4aQ9tj-KyAV7t_Kqj2_8hfe3Jb6g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Electrochromic vanadium–pentoxide–based films: Structural, electrochemical, and optical properties</title><source>AIP Digital Archive</source><creator>Talledo, A. ; Granqvist, C. G.</creator><creatorcontrib>Talledo, A. ; Granqvist, C. G.</creatorcontrib><description>Crystalline VO2.5 films were prepared by reactive dc magnetron sputtering followed by annealing posttreatment. Lithium was inserted electrochemically from an electrolyte so that LixVO2.5 (0&lt;x&lt;1.5) was formed. The evolution of the electromotive force (EMF) was recorded during Li intercalation. For lithiated samples, structure by x-ray diffraction, optical properties by spectrophotometry in the 0.3–2.5 μm range, infrared reflectance by spectrophotometry in the 400–1200 cm−1 interval, and the mechanical stress by beam deflectometry were studied. Changes in lattice parameters, phonon spectra, and stress levels gave a consistent picture of the structural evolution. Measurements of optical absorption and EMF were interpreted within a conceptual model of interband transitions between the O 2p band and a split V 3d band. Durability and reversibility of the Li intercalation/deintercalation were verified by potentiodynamic measurements. For comparison, the properties of highly disordered films were also measured.</description><identifier>ISSN: 0021-8979</identifier><identifier>EISSN: 1089-7550</identifier><identifier>DOI: 10.1063/1.359433</identifier><language>eng</language><ispartof>Journal of applied physics, 1995-05, Vol.77 (9), p.4655-4666</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c291t-7aa8148528efff7fca4f85366332e7eb17dbc3b4fa3c422e1276e10a4e2a40553</citedby><cites>FETCH-LOGICAL-c291t-7aa8148528efff7fca4f85366332e7eb17dbc3b4fa3c422e1276e10a4e2a40553</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Talledo, A.</creatorcontrib><creatorcontrib>Granqvist, C. G.</creatorcontrib><title>Electrochromic vanadium–pentoxide–based films: Structural, electrochemical, and optical properties</title><title>Journal of applied physics</title><description>Crystalline VO2.5 films were prepared by reactive dc magnetron sputtering followed by annealing posttreatment. Lithium was inserted electrochemically from an electrolyte so that LixVO2.5 (0&lt;x&lt;1.5) was formed. The evolution of the electromotive force (EMF) was recorded during Li intercalation. For lithiated samples, structure by x-ray diffraction, optical properties by spectrophotometry in the 0.3–2.5 μm range, infrared reflectance by spectrophotometry in the 400–1200 cm−1 interval, and the mechanical stress by beam deflectometry were studied. Changes in lattice parameters, phonon spectra, and stress levels gave a consistent picture of the structural evolution. Measurements of optical absorption and EMF were interpreted within a conceptual model of interband transitions between the O 2p band and a split V 3d band. Durability and reversibility of the Li intercalation/deintercalation were verified by potentiodynamic measurements. For comparison, the properties of highly disordered films were also measured.</description><issn>0021-8979</issn><issn>1089-7550</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1995</creationdate><recordtype>article</recordtype><recordid>eNo1kMtKxDAUhoMoOI6Cj9ClCzvm5NKk7mQYLzDgQl2X0_QEK-20JKnoznfwDX0SZxhd_Rf4_sXP2DnwBfBCXsFC6lJJecBmwG2ZG635IZtxLiC3pSmP2UmMb5wDWFnOmF915FIY3GsY-tZl77jBpp36n6_vkTZp-Ggb2voaIzWZb7s-XmdPKUwuTQG7y4z-cdrSuwI3TTaMaReyMQwjhdRSPGVHHrtIZ386Zy-3q-flfb5-vHtY3qxzJ0pIuUG0oKwWlrz3xjtU3mpZFFIKMlSDaWona-VROiUEgTAFAUdFAhXXWs7ZxX7XhSHGQL4aQ9tj-KyAV7t_Kqj2_8hfe3Jb6g</recordid><startdate>19950501</startdate><enddate>19950501</enddate><creator>Talledo, A.</creator><creator>Granqvist, C. G.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19950501</creationdate><title>Electrochromic vanadium–pentoxide–based films: Structural, electrochemical, and optical properties</title><author>Talledo, A. ; Granqvist, C. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c291t-7aa8148528efff7fca4f85366332e7eb17dbc3b4fa3c422e1276e10a4e2a40553</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1995</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Talledo, A.</creatorcontrib><creatorcontrib>Granqvist, C. G.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of applied physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Talledo, A.</au><au>Granqvist, C. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochromic vanadium–pentoxide–based films: Structural, electrochemical, and optical properties</atitle><jtitle>Journal of applied physics</jtitle><date>1995-05-01</date><risdate>1995</risdate><volume>77</volume><issue>9</issue><spage>4655</spage><epage>4666</epage><pages>4655-4666</pages><issn>0021-8979</issn><eissn>1089-7550</eissn><abstract>Crystalline VO2.5 films were prepared by reactive dc magnetron sputtering followed by annealing posttreatment. Lithium was inserted electrochemically from an electrolyte so that LixVO2.5 (0&lt;x&lt;1.5) was formed. The evolution of the electromotive force (EMF) was recorded during Li intercalation. For lithiated samples, structure by x-ray diffraction, optical properties by spectrophotometry in the 0.3–2.5 μm range, infrared reflectance by spectrophotometry in the 400–1200 cm−1 interval, and the mechanical stress by beam deflectometry were studied. Changes in lattice parameters, phonon spectra, and stress levels gave a consistent picture of the structural evolution. Measurements of optical absorption and EMF were interpreted within a conceptual model of interband transitions between the O 2p band and a split V 3d band. Durability and reversibility of the Li intercalation/deintercalation were verified by potentiodynamic measurements. For comparison, the properties of highly disordered films were also measured.</abstract><doi>10.1063/1.359433</doi><tpages>12</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0021-8979
ispartof Journal of applied physics, 1995-05, Vol.77 (9), p.4655-4666
issn 0021-8979
1089-7550
language eng
recordid cdi_crossref_primary_10_1063_1_359433
source AIP Digital Archive
title Electrochromic vanadium–pentoxide–based films: Structural, electrochemical, and optical properties
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-08T11%3A57%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Electrochromic%20vanadium%E2%80%93pentoxide%E2%80%93based%20films:%20Structural,%20electrochemical,%20and%20optical%20properties&rft.jtitle=Journal%20of%20applied%20physics&rft.au=Talledo,%20A.&rft.date=1995-05-01&rft.volume=77&rft.issue=9&rft.spage=4655&rft.epage=4666&rft.pages=4655-4666&rft.issn=0021-8979&rft.eissn=1089-7550&rft_id=info:doi/10.1063/1.359433&rft_dat=%3Ccrossref%3E10_1063_1_359433%3C/crossref%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true