A generalized rule for large piezoelectric response in perovskite oxide ceramics and its application for design of lead-free compositions

We present a general rule for the perovskite oxide ceramics: "A large piezoelectric constant in A B O 3 perovskite ceramics can be obtained by tuning the weight ratio of A and B sites, W A / W B or W B / W A , to 3. Piezoelectric constant decreases significantly when W A / W B or W B / W A is i...

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Veröffentlicht in:Journal of applied physics 2009-06, Vol.105 (11), p.114108-114108-6
Hauptverfasser: Ahn, Cheol-Woo, Maurya, Deepam, Park, Chee-Sung, Nahm, Sahn, Priya, Shashank
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container_issue 11
container_start_page 114108
container_title Journal of applied physics
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creator Ahn, Cheol-Woo
Maurya, Deepam
Park, Chee-Sung
Nahm, Sahn
Priya, Shashank
description We present a general rule for the perovskite oxide ceramics: "A large piezoelectric constant in A B O 3 perovskite ceramics can be obtained by tuning the weight ratio of A and B sites, W A / W B or W B / W A , to 3. Piezoelectric constant decreases significantly when W A / W B or W B / W A is in the range of 0.5-2.0, termed as forbidden zone." A comparative analysis was conducted for broad range of materials demonstrating the applicability of proposed rule. Further based on this rule optimized compositions in BaTiO 3 and alkali niobate based systems were developed. Polycrystalline ceramics in modified BaTiO 3 system were found to exhibit longitudinal piezoelectric coefficient ( d 33 ) of 330 pC/N, while alkali niobate ceramics showed d 33 of 294 pC/N.
doi_str_mv 10.1063/1.3142442
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title A generalized rule for large piezoelectric response in perovskite oxide ceramics and its application for design of lead-free compositions
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