Composite structure and size effect of barium titanate nanoparticles

Nanostructures of barium titanate ( BaTiO 3 ) nanoparticles were analyzed using a composite structure model. It was found that BaTiO 3 nanoparticles had a composite structure consisting of (i) inner tetragonal core, (ii) gradient lattice strain layer (GLSL), and (iii) surface cubic layer. The crysta...

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Veröffentlicht in:Applied physics letters 2008-11, Vol.93 (19), p.192914-192914-3
Hauptverfasser: Hoshina, Takuya, Wada, Satoshi, Kuroiwa, Yoshihiro, Tsurumi, Takaaki
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Wada, Satoshi
Kuroiwa, Yoshihiro
Tsurumi, Takaaki
description Nanostructures of barium titanate ( BaTiO 3 ) nanoparticles were analyzed using a composite structure model. It was found that BaTiO 3 nanoparticles had a composite structure consisting of (i) inner tetragonal core, (ii) gradient lattice strain layer (GLSL), and (iii) surface cubic layer. The crystal structure of each region did not depend on particle size while the volume fraction of the GLSL and the surface cubic layer increased with decreasing the particle size. These results suggested that the size effect of BaTiO 3 nanoparticles originated from the composite structure.
doi_str_mv 10.1063/1.3027067
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title Composite structure and size effect of barium titanate nanoparticles
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