Residual strain in ZnO nanowires grown by catalyst-free chemical vapor deposition on GaN/sapphire (0001)

ZnO nanowires were grown on 2 - μ m -thick GaN templates by chemical vapor deposition without employing any metal catalysts. The GaN template was deposited by metal-organic chemical vapor deposition on a c -plane sapphire substrate. The diameters of the resulting nanowires were in the range of 40 -...

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Veröffentlicht in:Applied physics letters 2008-05, Vol.92 (20), p.203110-203110-3
Hauptverfasser: Tsao, F. C., Chen, J. Y., Kuo, C. H., Chi, G. C., Pan, C. J., Huang, P. J., Tun, C. J., Pong, B. J., Hsueh, T. H., Chang, C. Y., Pearton, S. J., Ren, F.
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container_end_page 203110-3
container_issue 20
container_start_page 203110
container_title Applied physics letters
container_volume 92
creator Tsao, F. C.
Chen, J. Y.
Kuo, C. H.
Chi, G. C.
Pan, C. J.
Huang, P. J.
Tun, C. J.
Pong, B. J.
Hsueh, T. H.
Chang, C. Y.
Pearton, S. J.
Ren, F.
description ZnO nanowires were grown on 2 - μ m -thick GaN templates by chemical vapor deposition without employing any metal catalysts. The GaN template was deposited by metal-organic chemical vapor deposition on a c -plane sapphire substrate. The diameters of the resulting nanowires were in the range of 40 - 250 nm depending on growth time. The ZnO nanowires were vertically well aligned with uniform length, diameter, and distribution density as revealed by electron microscopy. X-ray diffraction spectra showed that ZnO grew in single c -axis orientation with the c axis normal to the GaN basal plane, indicating a heteroepitaxial relationship of ( 0002 ) Zn O || ( 0002 ) Ga N . The lattice constant of the c axis of the ZnO nanowires with diameter of 40 nm was 5.211 Å , which is larger than that of bulk ZnO ( 5.207 Å ) . The ZnO nanowires exhibit a residual tensile strain along the c axis, which decreases with increasing diameter.
doi_str_mv 10.1063/1.2936090
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C. ; Chen, J. Y. ; Kuo, C. H. ; Chi, G. C. ; Pan, C. J. ; Huang, P. J. ; Tun, C. J. ; Pong, B. J. ; Hsueh, T. H. ; Chang, C. Y. ; Pearton, S. J. ; Ren, F.</creator><creatorcontrib>Tsao, F. C. ; Chen, J. Y. ; Kuo, C. H. ; Chi, G. C. ; Pan, C. J. ; Huang, P. J. ; Tun, C. J. ; Pong, B. J. ; Hsueh, T. H. ; Chang, C. Y. ; Pearton, S. J. ; Ren, F.</creatorcontrib><description>ZnO nanowires were grown on 2 - μ m -thick GaN templates by chemical vapor deposition without employing any metal catalysts. The GaN template was deposited by metal-organic chemical vapor deposition on a c -plane sapphire substrate. The diameters of the resulting nanowires were in the range of 40 - 250 nm depending on growth time. The ZnO nanowires were vertically well aligned with uniform length, diameter, and distribution density as revealed by electron microscopy. 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title Residual strain in ZnO nanowires grown by catalyst-free chemical vapor deposition on GaN/sapphire (0001)
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