Extremely low-voltage driving of organic light-emitting diodes with a Cs-doped phenyldipyrenylphosphine oxide layer as an electron-injection layer

We demonstrated efficient electron injection and transport in organic light-emitting diodes using an electron-transport layer (ETL) composed of a Cs and phenyldipyrenylphosphine oxide (POPy2) co-deposited layer. In particular, an ETL composed of a Cs:POPy2 layer with an atom:molar ratio of 1:2 demon...

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Veröffentlicht in:Applied physics letters 2005-01, Vol.86 (3)
Hauptverfasser: Oyamada, Takahito, Sasabe, Hiroyuki, Adachi, Chihaya, Murase, Seiichiro, Tominaga, Tsuyoshi, Maeda, Chiharu
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container_title Applied physics letters
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creator Oyamada, Takahito
Sasabe, Hiroyuki
Adachi, Chihaya
Murase, Seiichiro
Tominaga, Tsuyoshi
Maeda, Chiharu
description We demonstrated efficient electron injection and transport in organic light-emitting diodes using an electron-transport layer (ETL) composed of a Cs and phenyldipyrenylphosphine oxide (POPy2) co-deposited layer. In particular, an ETL composed of a Cs:POPy2 layer with an atom:molar ratio of 1:2 demonstrated an extremely low driving voltage, resulting in a high current density of 100mA∕cm2 at an applied voltage of only 3.9 V. The results of Kelvin probe and absorption measurements indicated that the formation of a CsAl alloy layer at the Cs:POPy2/Al cathode interface and the charge-transfer complex between the Cs and POPy2 contributed to enhancing the efficiency of electron injection and transport, respectively.
doi_str_mv 10.1063/1.1852707
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title Extremely low-voltage driving of organic light-emitting diodes with a Cs-doped phenyldipyrenylphosphine oxide layer as an electron-injection layer
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