Study of the Isotopic Disproportionation Reaction between Light and Heavy Water Using a Pulsed-Molecular-Beam Mass Spectrometer

Isotopic exchange equilibrium in the disproportionation reaction H2O+D2O=2 HDO was studied at 0° and 25° and over a range of deuterium compositions using a pulsed-molecular-beam mass spectrometer. The equilibrium constant K was found to be 3.75±0.07 at both temperatures. The pulsed-beam mass spectro...

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Veröffentlicht in:	The Journal of chemical physics 1967-03, Vol.46 (6), p.2253-2257
Hauptverfasser:	Pyper, J. W., Newbury, R. S., Barton, G. W.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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