Collisional Transition Probabilities for Vibrational Deactivation of Chemically Activated sec -Butyl Radicals. The Rare Gases

Vibrationally excited sec-butyl radicals, having a narrow range of energies above 40 kcal mole−1, were produced in a heat bath of cis-butene-2-rare-gas mixtures by H addition to cis-butene-2. He, Ne, Ar, and Kr were used. Two competing reactions of the chemically activated radicals, decomposition by...

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