Spectroscopic Studies of Rotational Isomerism. V. The Infra-Red Absorption Spectra of Six Solid Hydrocarbons in the Region 1600–650 cm−1

Spectroscopic Studies of Rotational Isomerism. V. The Infra-Red Absorption Spectra of Six Solid Hydrocarbons in the Region 1600–650 cm−1

The infra-red absorption spectra of six hydrocarbons have been measured at low temperatures. As with the Raman spectra, a considerable degree of simplification occurs on freezing, due to the existence of only one rotational isomer in the solid state. It has not proved possible to obtain accurate val...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:The Journal of chemical physics 1950-01, Vol.18 (1), p.51-54
Hauptverfasser: Axford, D. W. E., Rank, D. H.
Format: Artikel
Sprache:eng ; jpn
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 54
container_issue 1
container_start_page 51
container_title The Journal of chemical physics
container_volume 18
creator Axford, D. W. E.
Rank, D. H.
description The infra-red absorption spectra of six hydrocarbons have been measured at low temperatures. As with the Raman spectra, a considerable degree of simplification occurs on freezing, due to the existence of only one rotational isomer in the solid state. It has not proved possible to obtain accurate values of the energy differences between the isomers from this data. The possible ways of obtaining energy difference from spectroscopic data are discussed.
doi_str_mv 10.1063/1.1747455
format Article
fullrecord <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1063_1_1747455</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1063_1_1747455</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1408-4200eee90a02ff598fb0a213c257bf0dbdb5ba2267cc20a1e801838fef54d8943</originalsourceid><addsrcrecordid>eNotkL1OwzAUhS0EEqUw8AZeGRLudZy_saqAVqqE1BTWyHZsMGriyA4S3RgZmOANeRIatdNZvu9I5xByjRAjZMktxpjznKfpCZkgFGWUZyWckgkAw6jMIDsnFyG8AQDmjE_Id9VrNXgXlOutotXw3lgdqDN07QYxWNeJLV0G12pvQxvT55huXjVddsaLaK0bOpPB-X4E6aFKjHJlP2jltrahi13jnRJeui5Q29Fhb6_1y8hjBvD3-ZulQFX79_WDl-TMiG3QV8eckqf7u818Ea0eH5bz2SpSyKGIOAPQWpcggBmTloWRIBgmiqW5NNDIRqZSMJblSjEQqAvAIimMNilvipInU3Jz6FX74cFrU_fetsLvaoR6vLHG-nhj8g_t-GYk</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Spectroscopic Studies of Rotational Isomerism. V. The Infra-Red Absorption Spectra of Six Solid Hydrocarbons in the Region 1600–650 cm−1</title><source>AIP Digital Archive</source><creator>Axford, D. W. E. ; Rank, D. H.</creator><creatorcontrib>Axford, D. W. E. ; Rank, D. H.</creatorcontrib><description>The infra-red absorption spectra of six hydrocarbons have been measured at low temperatures. As with the Raman spectra, a considerable degree of simplification occurs on freezing, due to the existence of only one rotational isomer in the solid state. It has not proved possible to obtain accurate values of the energy differences between the isomers from this data. The possible ways of obtaining energy difference from spectroscopic data are discussed.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.1747455</identifier><language>eng ; jpn</language><ispartof>The Journal of chemical physics, 1950-01, Vol.18 (1), p.51-54</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1408-4200eee90a02ff598fb0a213c257bf0dbdb5ba2267cc20a1e801838fef54d8943</citedby><cites>FETCH-LOGICAL-c1408-4200eee90a02ff598fb0a213c257bf0dbdb5ba2267cc20a1e801838fef54d8943</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Axford, D. W. E.</creatorcontrib><creatorcontrib>Rank, D. H.</creatorcontrib><title>Spectroscopic Studies of Rotational Isomerism. V. The Infra-Red Absorption Spectra of Six Solid Hydrocarbons in the Region 1600–650 cm−1</title><title>The Journal of chemical physics</title><description>The infra-red absorption spectra of six hydrocarbons have been measured at low temperatures. As with the Raman spectra, a considerable degree of simplification occurs on freezing, due to the existence of only one rotational isomer in the solid state. It has not proved possible to obtain accurate values of the energy differences between the isomers from this data. The possible ways of obtaining energy difference from spectroscopic data are discussed.</description><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1950</creationdate><recordtype>article</recordtype><recordid>eNotkL1OwzAUhS0EEqUw8AZeGRLudZy_saqAVqqE1BTWyHZsMGriyA4S3RgZmOANeRIatdNZvu9I5xByjRAjZMktxpjznKfpCZkgFGWUZyWckgkAw6jMIDsnFyG8AQDmjE_Id9VrNXgXlOutotXw3lgdqDN07QYxWNeJLV0G12pvQxvT55huXjVddsaLaK0bOpPB-X4E6aFKjHJlP2jltrahi13jnRJeui5Q29Fhb6_1y8hjBvD3-ZulQFX79_WDl-TMiG3QV8eckqf7u818Ea0eH5bz2SpSyKGIOAPQWpcggBmTloWRIBgmiqW5NNDIRqZSMJblSjEQqAvAIimMNilvipInU3Jz6FX74cFrU_fetsLvaoR6vLHG-nhj8g_t-GYk</recordid><startdate>19500101</startdate><enddate>19500101</enddate><creator>Axford, D. W. E.</creator><creator>Rank, D. H.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19500101</creationdate><title>Spectroscopic Studies of Rotational Isomerism. V. The Infra-Red Absorption Spectra of Six Solid Hydrocarbons in the Region 1600–650 cm−1</title><author>Axford, D. W. E. ; Rank, D. H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1408-4200eee90a02ff598fb0a213c257bf0dbdb5ba2267cc20a1e801838fef54d8943</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng ; jpn</language><creationdate>1950</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Axford, D. W. E.</creatorcontrib><creatorcontrib>Rank, D. H.</creatorcontrib><collection>CrossRef</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Axford, D. W. E.</au><au>Rank, D. H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Spectroscopic Studies of Rotational Isomerism. V. The Infra-Red Absorption Spectra of Six Solid Hydrocarbons in the Region 1600–650 cm−1</atitle><jtitle>The Journal of chemical physics</jtitle><date>1950-01-01</date><risdate>1950</risdate><volume>18</volume><issue>1</issue><spage>51</spage><epage>54</epage><pages>51-54</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>The infra-red absorption spectra of six hydrocarbons have been measured at low temperatures. As with the Raman spectra, a considerable degree of simplification occurs on freezing, due to the existence of only one rotational isomer in the solid state. It has not proved possible to obtain accurate values of the energy differences between the isomers from this data. The possible ways of obtaining energy difference from spectroscopic data are discussed.</abstract><doi>10.1063/1.1747455</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0021-9606
ispartof The Journal of chemical physics, 1950-01, Vol.18 (1), p.51-54
issn 0021-9606
1089-7690
language eng ; jpn
recordid cdi_crossref_primary_10_1063_1_1747455
source AIP Digital Archive
title Spectroscopic Studies of Rotational Isomerism. V. The Infra-Red Absorption Spectra of Six Solid Hydrocarbons in the Region 1600–650 cm−1
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T15%3A19%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Spectroscopic%20Studies%20of%20Rotational%20Isomerism.%20V.%20The%20Infra-Red%20Absorption%20Spectra%20of%20Six%20Solid%20Hydrocarbons%20in%20the%20Region%201600%E2%80%93650%20cm%E2%88%921&rft.jtitle=The%20Journal%20of%20chemical%20physics&rft.au=Axford,%20D.%20W.%20E.&rft.date=1950-01-01&rft.volume=18&rft.issue=1&rft.spage=51&rft.epage=54&rft.pages=51-54&rft.issn=0021-9606&rft.eissn=1089-7690&rft_id=info:doi/10.1063/1.1747455&rft_dat=%3Ccrossref%3E10_1063_1_1747455%3C/crossref%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true