Crystal Field Splitting of Energy Levels of Thulium Ethylsulfate
The operator-equivalent method was employed to calculate the theoretical splitting of electronic energy levels 3P2, 1D2, 3F2, 3F3, 3F4, 1G4, and 3H6 in Tm(C2H5SO4)3·9H2O. Intermediate field corrections were made to α, β, and γ. A first-order perturbation treatment on Tm3+ (4f12) in C3h symmetry, usi...
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| Veröffentlicht in: | Journal of Chemical Physics (U.S.) 1960-05, Vol.32 (5), p.1531-1534 |
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| container_end_page | 1534 |
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| container_issue | 5 |
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| container_title | Journal of Chemical Physics (U.S.) |
| container_volume | 32 |
| creator | Gruber, John B. Conway, John G. |
| description | The operator-equivalent method was employed to calculate the theoretical splitting of electronic energy levels 3P2, 1D2, 3F2, 3F3, 3F4, 1G4, and 3H6 in Tm(C2H5SO4)3·9H2O. Intermediate field corrections were made to α, β, and γ. A first-order perturbation treatment on Tm3+ (4f12) in C3h symmetry, using crystal-field parameters A20〈r2〉=13 cm—1, A40〈r4〉=—80 cm—1, A60〈r6〉=—32 cm—1, and A66〈r6〉=300 cm—1, predicts the position of the crystal quantum states in reasonable agreement with experiment. |
| doi_str_mv | 10.1063/1.1730954 |
| format | Article |
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Intermediate field corrections were made to α, β, and γ. A first-order perturbation treatment on Tm3+ (4f12) in C3h symmetry, using crystal-field parameters A20〈r2〉=13 cm—1, A40〈r4〉=—80 cm—1, A60〈r6〉=—32 cm—1, and A66〈r6〉=300 cm—1, predicts the position of the crystal quantum states in reasonable agreement with experiment.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.1730954</identifier><language>eng</language><subject>ATOMIC MODELS ; CHEMISTRY ; CRYSTALS ; DECOMPOSITION ; ENERGY ; ENERGY LEVELS ; IONS ; LEVELS ; MATHEMATICS ; PERTURBATION THEORY ; QUANTUM MECHANICS ; THULIUM SULFATES</subject><ispartof>Journal of Chemical Physics (U.S.), 1960-05, Vol.32 (5), p.1531-1534</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c355t-39dd7eea4c3ef74b3bad3c7197c9288ebabbf62abb279028755aa015551c8f743</citedby><cites>FETCH-LOGICAL-c355t-39dd7eea4c3ef74b3bad3c7197c9288ebabbf62abb279028755aa015551c8f743</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/4181575$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Gruber, John B.</creatorcontrib><creatorcontrib>Conway, John G.</creatorcontrib><creatorcontrib>Univ. of California, Berkeley</creatorcontrib><title>Crystal Field Splitting of Energy Levels of Thulium Ethylsulfate</title><title>Journal of Chemical Physics (U.S.)</title><description>The operator-equivalent method was employed to calculate the theoretical splitting of electronic energy levels 3P2, 1D2, 3F2, 3F3, 3F4, 1G4, and 3H6 in Tm(C2H5SO4)3·9H2O. Intermediate field corrections were made to α, β, and γ. A first-order perturbation treatment on Tm3+ (4f12) in C3h symmetry, using crystal-field parameters A20〈r2〉=13 cm—1, A40〈r4〉=—80 cm—1, A60〈r6〉=—32 cm—1, and A66〈r6〉=300 cm—1, predicts the position of the crystal quantum states in reasonable agreement with experiment.</description><subject>ATOMIC MODELS</subject><subject>CHEMISTRY</subject><subject>CRYSTALS</subject><subject>DECOMPOSITION</subject><subject>ENERGY</subject><subject>ENERGY LEVELS</subject><subject>IONS</subject><subject>LEVELS</subject><subject>MATHEMATICS</subject><subject>PERTURBATION THEORY</subject><subject>QUANTUM MECHANICS</subject><subject>THULIUM SULFATES</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1960</creationdate><recordtype>article</recordtype><recordid>eNotkDFPwzAUhC0EEqEw8A8iNoaU9-I4jjdQ1QJSJQbKbDnOS2PkJlXsIuXf06pd7qTTdzccY48Ic4SSv-AcJQcliiuWIFQqk6WCa5YA5JipEspbdhfCLwCgzIuEvS7GKUTj05Uj36Tfe-9idP02Hdp02dO4ndI1_ZEPp2DTHbw77NJl7CYfDr41ke7ZTWt8oIeLz9jParlZfGTrr_fPxds6s1yImHHVNJLIFJZTK4ua16bhVqKSVuVVRbWp67bMj5pLBXklhTAGUAiBtjoW-Iw9nXeHEJ0O1kWynR36nmzUBVYopDhCz2fIjkMII7V6P7qdGSeNoE__aNSXf_g_Ax9XCA</recordid><startdate>19600501</startdate><enddate>19600501</enddate><creator>Gruber, John B.</creator><creator>Conway, John G.</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19600501</creationdate><title>Crystal Field Splitting of Energy Levels of Thulium Ethylsulfate</title><author>Gruber, John B. ; Conway, John G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c355t-39dd7eea4c3ef74b3bad3c7197c9288ebabbf62abb279028755aa015551c8f743</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1960</creationdate><topic>ATOMIC MODELS</topic><topic>CHEMISTRY</topic><topic>CRYSTALS</topic><topic>DECOMPOSITION</topic><topic>ENERGY</topic><topic>ENERGY LEVELS</topic><topic>IONS</topic><topic>LEVELS</topic><topic>MATHEMATICS</topic><topic>PERTURBATION THEORY</topic><topic>QUANTUM MECHANICS</topic><topic>THULIUM SULFATES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gruber, John B.</creatorcontrib><creatorcontrib>Conway, John G.</creatorcontrib><creatorcontrib>Univ. of California, Berkeley</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of Chemical Physics (U.S.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gruber, John B.</au><au>Conway, John G.</au><aucorp>Univ. of California, Berkeley</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal Field Splitting of Energy Levels of Thulium Ethylsulfate</atitle><jtitle>Journal of Chemical Physics (U.S.)</jtitle><date>1960-05-01</date><risdate>1960</risdate><volume>32</volume><issue>5</issue><spage>1531</spage><epage>1534</epage><pages>1531-1534</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>The operator-equivalent method was employed to calculate the theoretical splitting of electronic energy levels 3P2, 1D2, 3F2, 3F3, 3F4, 1G4, and 3H6 in Tm(C2H5SO4)3·9H2O. Intermediate field corrections were made to α, β, and γ. A first-order perturbation treatment on Tm3+ (4f12) in C3h symmetry, using crystal-field parameters A20〈r2〉=13 cm—1, A40〈r4〉=—80 cm—1, A60〈r6〉=—32 cm—1, and A66〈r6〉=300 cm—1, predicts the position of the crystal quantum states in reasonable agreement with experiment.</abstract><doi>10.1063/1.1730954</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Journal of Chemical Physics (U.S.), 1960-05, Vol.32 (5), p.1531-1534 |
| issn | 0021-9606 1089-7690 |
| language | eng |
| recordid | cdi_crossref_primary_10_1063_1_1730954 |
| source | AIP Digital Archive |
| subjects | ATOMIC MODELS CHEMISTRY CRYSTALS DECOMPOSITION ENERGY ENERGY LEVELS IONS LEVELS MATHEMATICS PERTURBATION THEORY QUANTUM MECHANICS THULIUM SULFATES |
| title | Crystal Field Splitting of Energy Levels of Thulium Ethylsulfate |
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