Equilibrium in the Exchange of Hydrogen between Arsine and Water

Equilibrium in the Exchange of Hydrogen between Arsine and Water

The equilibrium constant for the reaction AsH2D(g)+H2O(l)⇌AsH3(g)+HDO(l) has been measured at 25.4° and found to be 1.89±0.02, corresponding to a value in the gas phase of 1.77±0.02. With the known vibrational spectra of AsH3 and AsH3—d3 the gas phase equilibrium constant was calculated at 25.4°, K2...

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Veröffentlicht in:Journal of Chemical Physics (U.S.) 1959-10, Vol.31 (4), p.889-891
Hauptverfasser: Zeltmann, Alfred H., Gerhold, George
Format: Artikel
Sprache:eng
Schlagworte:
ARSENIC HYDRIDES
CHEMISTRY
DEUTERIUM COMPOUNDS
GASES
HYDROGEN
ION EXCHANGE
ISOTOPIC EXCHANGE
MEASURED VALUES
REACTION KINETICS
SPECTRA
WATER
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container_issue 4
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container_title Journal of Chemical Physics (U.S.)
container_volume 31
creator Zeltmann, Alfred H.
Gerhold, George
description The equilibrium constant for the reaction AsH2D(g)+H2O(l)⇌AsH3(g)+HDO(l) has been measured at 25.4° and found to be 1.89±0.02, corresponding to a value in the gas phase of 1.77±0.02. With the known vibrational spectra of AsH3 and AsH3—d3 the gas phase equilibrium constant was calculated at 25.4°, K2=0.777e258/T=1.84.
doi_str_mv 10.1063/1.1730544
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With the known vibrational spectra of AsH3 and AsH3—d3 the gas phase equilibrium constant was calculated at 25.4°, K2=0.777e258/T=1.84.</description><subject>ARSENIC HYDRIDES</subject><subject>CHEMISTRY</subject><subject>DEUTERIUM COMPOUNDS</subject><subject>GASES</subject><subject>HYDROGEN</subject><subject>ION EXCHANGE</subject><subject>ISOTOPIC EXCHANGE</subject><subject>MEASURED VALUES</subject><subject>REACTION KINETICS</subject><subject>SPECTRA</subject><subject>WATER</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1959</creationdate><recordtype>article</recordtype><recordid>eNotkM1OAjEYABujiYgefIPGm4fFr7-7e5MQFBMSLyQeN932K9RAV9sS5e3FwGkukzkMIfcMJgy0eGITVgtQUl6QEYOmrWrdwiUZAXBWtRr0NbnJ-RMAWM3liDzPv_dhG_oU9jsaIi0bpPNfuzFxjXTwdHFwaVhjpD2WHzxymnKISE109MMUTLfkypttxrszx2T1Ml_NFtXy_fVtNl1WlitdKqOsEoI74UEq09esAQmNU1rK1jbSceV656DxDBCtt0Yyg75G0yqNzIgxeThlh1xCl20oaDd2iBFt6STn0Gp9lB5Pkk1Dzgl995XCzqRDx6D739Ox7rxH_AEp3FZJ</recordid><startdate>19591001</startdate><enddate>19591001</enddate><creator>Zeltmann, Alfred H.</creator><creator>Gerhold, George</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19591001</creationdate><title>Equilibrium in the Exchange of Hydrogen between Arsine and Water</title><author>Zeltmann, Alfred H. ; Gerhold, George</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c256t-a5c5332d3f045ab7180408d56449c84d25dbdd08f10eecfca41aef7ea956e1a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1959</creationdate><topic>ARSENIC HYDRIDES</topic><topic>CHEMISTRY</topic><topic>DEUTERIUM COMPOUNDS</topic><topic>GASES</topic><topic>HYDROGEN</topic><topic>ION EXCHANGE</topic><topic>ISOTOPIC EXCHANGE</topic><topic>MEASURED VALUES</topic><topic>REACTION KINETICS</topic><topic>SPECTRA</topic><topic>WATER</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zeltmann, Alfred H.</creatorcontrib><creatorcontrib>Gerhold, George</creatorcontrib><creatorcontrib>Los Alamos Scientific Lab., N. 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With the known vibrational spectra of AsH3 and AsH3—d3 the gas phase equilibrium constant was calculated at 25.4°, K2=0.777e258/T=1.84.</abstract><doi>10.1063/1.1730544</doi><tpages>3</tpages></addata></record>
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subjects ARSENIC HYDRIDES
CHEMISTRY
DEUTERIUM COMPOUNDS
GASES
HYDROGEN
ION EXCHANGE
ISOTOPIC EXCHANGE
MEASURED VALUES
REACTION KINETICS
SPECTRA
WATER
title Equilibrium in the Exchange of Hydrogen between Arsine and Water
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