Gas-Phase Photolysis of Methyl Iodide. Reactions of Hot Methyl Radicals with Added Organic Compounds

The photolysis of CH3I and CD3I at 2537 and 3130 Å has been investigated in the presence of CD3CH3, C2D6, CH3CD2CH3, CD3CH2CD3, C4H10–C4D10 (1:1) mixtures, (CH3)3CD, (CH3)3CCD3, C6H6, C6H12, CH3OCH3, CH3COOCD3, CD3OH, C2D5OH, and CD3CH2OH. All mixtures were saturated with iodine in order to prevent...

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Veröffentlicht in:	Journal of Chemical Physics (U.S.) 1964-09, Vol.41 (6), p.1865-1871
Hauptverfasser:	Doepker, Richard D., Ausloos, P.
Format:	Artikel
Sprache:	eng
Schlagworte:	ACETIC ACID BENZENE BUTANE BUTANOL CHEMICAL REACTIONS CHEMISTRY CONFIGURATION CYCLOALKANES DEUTERIUM COMPOUNDS ESTERS ETHANE ETHANOL ETHERS FREQUENCY GASES HEXANE IODIDES IODINATED HYDROCARBONS ISOTOPE EFFECTS LABELLED COMPOUNDS METHANE METHANOL METHYL RADICALS MIXING ORGANIC COMPOUNDS ORGANIC IODINE COMPOUNDS PHOTOLYSIS PROPANE QUANTUM MECHANICS STATISTICS THERMODYNAMICS
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