ESR Study of the Crystallographic Phases in Zn2P2O7:Mn and Zn2P2O7:Cu

The ESR spectra of Mn++ and Cu++ in Zn2P2O7 have been studied between room temperature and 200°C. A first-order phase transition is found at 132°C and a transition of higher thermodynamic order occurs near 155°C. The space group of Zn2P2O7 above 155°C is determined to be C-2/m, whereas between 132°...

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Veröffentlicht in:The Journal of chemical physics 1964-08, Vol.41 (3), p.806-813
Hauptverfasser: Chambers, J. G., Datars, W. R., Calvo, C.
Format: Artikel
Sprache:eng
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