Primary Pyroelectric Effect in the PZT 95/5 Ceramic

An expression of the thermodynamic potential is examined in terms of the primary and secondary pyroelectric coefficients of a poled ferroelectric ceramic. Anisotropic expansion and zero electric field conditions are assumed. The pyroelectric coefficient is applied to the composition, Pb(Zr0.95Ti0.05...

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Veröffentlicht in:Journal of Applied Physics (U.S.) 1964-06, Vol.35 (6), p.1767-1770
Hauptverfasser: Wentz, J. L., Kennedy, L. Z.
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container_title Journal of Applied Physics (U.S.)
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creator Wentz, J. L.
Kennedy, L. Z.
description An expression of the thermodynamic potential is examined in terms of the primary and secondary pyroelectric coefficients of a poled ferroelectric ceramic. Anisotropic expansion and zero electric field conditions are assumed. The pyroelectric coefficient is applied to the composition, Pb(Zr0.95Ti0.05)O3 (PZT 95/5) with 1 wt. % of Nb2O5, for which a complete set of elastic, piezoelectric, thermoelastic, and pyroelectric coefficients were determined. A value of −26.8×10−9C/cm2-°C was found for the total pyroelectric coefficient of which +3.77×10−9 was contributed towards the piezoelectric or secondary effect; therefore, −30.6×10−9C/cm2-°C is reported for the primary pyroelectric coefficient for this material over the temperature range 25°–50°C.
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subjects ANISOTROPY
CERAMICS
CRYSTALS
ELASTICITY
ELECTRIC FIELDS
ELECTRICITY
EXPANSION
HEATING
LEAD OXIDES
MEASURED VALUES
METALS, CERAMICS, AND OTHER MATERIALS
NIOBIUM OXIDES
PIEZOELECTRICITY
TEMPERATURE
THERMODYNAMICS
TITANIUM OXIDES
ZIRCONIUM OXIDES
title Primary Pyroelectric Effect in the PZT 95/5 Ceramic
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