Vibrations and Thermodynamic Properties of Hexasulfur

Vibrations and Thermodynamic Properties of Hexasulfur

Infrared and Raman spectra of Engel's sulfur S6, including complete polarization data for solutions of S6, provide assignments for the fundamental modes. Force fields that have been successful for S8 provide good agreement with the S6 spectra. A force model previously used for S8 is shown to be...

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Veröffentlicht in:The Journal of chemical physics 1967-01, Vol.47 (11), p.4320-4324
Hauptverfasser: Berkowitz, Joseph, Chupka, W. A., Bromels, Edward, Belford, R. Linn
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container_end_page 4324
container_issue 11
container_start_page 4320
container_title The Journal of chemical physics
container_volume 47
creator Berkowitz, Joseph
Chupka, W. A.
Bromels, Edward
Belford, R. Linn
description Infrared and Raman spectra of Engel's sulfur S6, including complete polarization data for solutions of S6, provide assignments for the fundamental modes. Force fields that have been successful for S8 provide good agreement with the S6 spectra. A force model previously used for S8 is shown to be incorrect. Thermodynamic properties (HT°—H0°, FT°—H0°, ST°—S0°) for gaseous S6 are tabulated from 100° to 3000°K. The spectroscopic values S400° (92.8 eu) and S298° (84.6 eu) are in excellent agreement with those derived from thermodynamic measurements.
doi_str_mv 10.1063/1.1701632
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title Vibrations and Thermodynamic Properties of Hexasulfur
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