Infrared Spectrum of Hydrogen Sulfide from 2200–2800 cm−1
The absorption of hydrogen sulfide from 2200 to 2800 cm−1 has been observed under high resolution. It can be accounted for by two bands having excited states (n1,n2,n3) = (0,2,0), and (1,0,0). A novel feature of this analysis is the assignment of the strong absorption in the high-frequency portion o...
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Veröffentlicht in: | The Journal of chemical physics 1956-01, Vol.24 (1), p.35-38 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The absorption of hydrogen sulfide from 2200 to 2800 cm−1 has been observed under high resolution. It can be accounted for by two bands having excited states (n1,n2,n3) = (0,2,0), and (1,0,0). A novel feature of this analysis is the assignment of the strong absorption in the high-frequency portion of this region as arising from the transition (0,0,0)→(1,0,0). The parameters giving the best fits to the observed absorption are: A*B*C*ν0(0,2,0)11.0999.4434.6102353.93 cm−1(1,0,0)10.2498.8314.6632614.56 cm−1.It was not possible to assign enough transitions in the (0,0,1) band to determine a unique set of parameters. |
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ISSN: | 0021-9606 1089-7690 |
DOI: | 10.1063/1.1700848 |