Infrared Spectrum of Hydrogen Sulfide from 2200–2800 cm−1

The absorption of hydrogen sulfide from 2200 to 2800 cm−1 has been observed under high resolution. It can be accounted for by two bands having excited states (n1,n2,n3) = (0,2,0), and (1,0,0). A novel feature of this analysis is the assignment of the strong absorption in the high-frequency portion o...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:The Journal of chemical physics 1956-01, Vol.24 (1), p.35-38
Hauptverfasser: Allen, Harry C., Blaine, L. R., Plyer, Earle K., Cross, Paul C.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The absorption of hydrogen sulfide from 2200 to 2800 cm−1 has been observed under high resolution. It can be accounted for by two bands having excited states (n1,n2,n3) = (0,2,0), and (1,0,0). A novel feature of this analysis is the assignment of the strong absorption in the high-frequency portion of this region as arising from the transition (0,0,0)→(1,0,0). The parameters giving the best fits to the observed absorption are: A*B*C*ν0(0,2,0)11.0999.4434.6102353.93 cm−1(1,0,0)10.2498.8314.6632614.56 cm−1.It was not possible to assign enough transitions in the (0,0,1) band to determine a unique set of parameters.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1700848