Mercury-Sensitized Photolysis of Propylene Primary and Radical Reactions

A description is given of the mercury-sensitized photolysis of propylene and mixtures of propylene with H2, D2, and propylene-d6 at 26°C using 253.7 and 184.9-nm light. There are at least five primary steps: C3H6*→H+C3H5,  C3H6*→CH3+C2H3,  C3H6*→cyclopropane,  C3H6*→CH4+C2H2,  C3H6*→H2+(C3H4).The ra...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of Chemical Physics (U.S.) 1965-02, Vol.42 (4), p.1262-1268
Hauptverfasser:	Heller, Carl A., Gordon, Alvin S.
Format:	Artikel
Sprache:	eng
Schlagworte:	CHEMISTRY DECOMPOSITION DEUTERIUM COMPOUNDS FREQUENCY HYDROGEN LABELLED COMPOUNDS LIGHT MERCURY PHOTOCHEMISTRY PROPYLENE Radiation Chemistry SENSITIVITY
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!