Three-step photoselection and the assignment of the electronic states of the benzyl radical

A contradiction between assignments of the first excited state of the benzyl radical, originally made by three-step photoselection in rigid solutions, and later by gas-phase rotational analysis, has been resolved. The photochemically produced radical in a rigid solution can be subject to rotational...

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Veröffentlicht in:The Journal of chemical physics 1973-06, Vol.58 (11), p.4766-4775
Hauptverfasser: Friedrich, Donald M., Albrecht, A. C.
Format: Artikel
Sprache:eng
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