Permanent electric dipole moments and hyperfine interaction in ruthenium monocarbide, RuC
The [18.1]1∏←X 1∑+ band system of a molecular beam sample of RuC has been recorded field free and in the presence of a static electric field using high resolution laser induced fluorescence spectroscopy. The Stark shifts of the optical features for the 102RuC isotopomer were analyzed to produce perm...
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| Veröffentlicht in: | The Journal of chemical physics 2003-02, Vol.118 (6), p.2620-2625 |
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| container_title | The Journal of chemical physics |
| container_volume | 118 |
| creator | Steimle, Timothy C. Virgo, Wilton L. Brown, John M. |
| description | The [18.1]1∏←X 1∑+ band system of a molecular beam sample of RuC has been recorded field free and in the presence of a static electric field using high resolution laser induced fluorescence spectroscopy. The Stark shifts of the optical features for the 102RuC isotopomer were analyzed to produce permanent electric dipole moments of 3.31(4) and 4.09(14) D for the [18.1]1∏ and X 1∑+ states, respectively. The hyperfine structure associated with spectral features for the 101RuC and 99RuC isotopomers was analyzed to produce electric quadrupole and magnetic hyperfine coupling parameters. The hyperfine structure and dipole moments are interpreted using a molecular orbital correlation model and compared with predictions from electronic structure calculations and isovalent iron monocarbide, FeC. |
| doi_str_mv | 10.1063/1.1534586 |
| format | Article |
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| ispartof | The Journal of chemical physics, 2003-02, Vol.118 (6), p.2620-2625 |
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| source | AIP Journals Complete; AIP Digital Archive |
| title | Permanent electric dipole moments and hyperfine interaction in ruthenium monocarbide, RuC |
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