Dielectric properties of oriented PbZrO3 thin films grown by sol-gel process

Antiferroelectric PbZrO3 (PZ) films have been fabricated on LaNiO3/Pt/Ti/SiO2/Si substrates using a sol-gel process. The films with perovskite structure showed highly 〈001〉 preferred orientation. An antiferroelectric phase was identified by the presence of 1/4{110} superlattice spots in a [001] sele...

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Veröffentlicht in:Journal of applied physics 2002-10, Vol.92 (7), p.3990-3994
Hauptverfasser: Zhai, Jiwei, Yao, Y., Li, X., Hung, T. F., Xu, Z. K., Chen, Haydn, Colla, Eugene V., Wu, T. B.
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container_end_page 3994
container_issue 7
container_start_page 3990
container_title Journal of applied physics
container_volume 92
creator Zhai, Jiwei
Yao, Y.
Li, X.
Hung, T. F.
Xu, Z. K.
Chen, Haydn
Colla, Eugene V.
Wu, T. B.
description Antiferroelectric PbZrO3 (PZ) films have been fabricated on LaNiO3/Pt/Ti/SiO2/Si substrates using a sol-gel process. The films with perovskite structure showed highly 〈001〉 preferred orientation. An antiferroelectric phase was identified by the presence of 1/4{110} superlattice spots in a [001] selected area electron diffraction pattern. The field-induced antiferroelectric to ferroelectric phase switching was demonstrated at room temperature with full saturation and a maximum polarization of 40 μC/cm2. Dielectric properties were investigated as a function of both temperature and frequency. The presence of a conductive buffer layer of LaNiO3 on Pt/Ti/SiO2/Si substrate enabled the growth of high quality and highly oriented PZ antiferroelectric thin films that showed near zero remanent polarization and squared hysteresis loops.
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