Quantitative investigation of the kinetic energy release in metastable decay reactions of (O2)n=2–10+ ions: Evidence for a change in the metastable decay mechanism as a function of cluster size

Using a high resolution two sector field mass spectrometer of reversed geometry we have measured metastable fractions and mass-analyzed ion kinetic energy peaks for metastable decay reactions involving monomer evaporation via (O2)n+*→(O2)n−1++O2. Both, average kinetic energy release 〈KER〉 data deriv...

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Veröffentlicht in:The Journal of chemical physics 2002-05, Vol.116 (17), p.7583-7588
Hauptverfasser: Matt, S., Parajuli, R., Stamatovic, A., Scheier, P., Märk, T. D.
Format: Artikel
Sprache:eng
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