Rotational-state selective nuclear magnetic resonance spectra of hydrogen in a molecular trap

Rotational-state selective nuclear magnetic resonance spectra of hydrogen in a molecular trap

A nuclear magnetic resonance (NMR) study of the molecular quantum dynamics of hydrogen trapped in solid C60 is presented. Rotational-state selective NMR spectra are shown. The analysis of the spectra provides a direct map of the molecular orientational probability distribution and of the rotational...

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Veröffentlicht in:The Journal of chemical physics 2001-12, Vol.115 (24), p.11017-11020
Hauptverfasser: Tomaselli, M., Meier, B. H.
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container_title The Journal of chemical physics
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creator Tomaselli, M.
Meier, B. H.
description A nuclear magnetic resonance (NMR) study of the molecular quantum dynamics of hydrogen trapped in solid C60 is presented. Rotational-state selective NMR spectra are shown. The analysis of the spectra provides a direct map of the molecular orientational probability distribution and of the rotational wave functions. Perturbations of the free rotor behavior due to rotor-phonon interactions and due to the S6 symmetry of the confining cage potential are discussed.
doi_str_mv 10.1063/1.1429655
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title Rotational-state selective nuclear magnetic resonance spectra of hydrogen in a molecular trap
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