Mass spectra and photoelectron spectroscopy of negatively charged benzene clusters, (benzene)n− (n=53–124)

Mass spectra and photoelectron spectroscopy of negatively charged benzene clusters, (benzene)n− (n=53–124)

Negatively charged benzene clusters, (benzene)n−, were produced by injecting low- and high-energy electrons into an intense supersonic jet expansion. Threshold size of n=53 was observed by slow-electron attachment, while the smaller (benzene)n− with 2⩽n⩽52 were also observed through the fragmentatio...

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Veröffentlicht in:The Journal of chemical physics 2001-10, Vol.115 (13), p.5707-5710
Hauptverfasser: Mitsui, Masaaki, Nakajima, Atsushi, Kaya, Koji, Even, Uzi
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container_issue 13
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container_title The Journal of chemical physics
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creator Mitsui, Masaaki
Nakajima, Atsushi
Kaya, Koji
Even, Uzi
description Negatively charged benzene clusters, (benzene)n−, were produced by injecting low- and high-energy electrons into an intense supersonic jet expansion. Threshold size of n=53 was observed by slow-electron attachment, while the smaller (benzene)n− with 2⩽n⩽52 were also observed through the fragmentation of larger (benzene)n− by high-energy electron attachment. Photoelectron spectroscopy for (benzene)n− with n=53–124 has revealed a bulklike electron solvated state in (benzene)n⩾53− through the vertical detachment energies (VDEs) versus n−1/3 relationship.
doi_str_mv 10.1063/1.1407844
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title Mass spectra and photoelectron spectroscopy of negatively charged benzene clusters, (benzene)n− (n=53–124)
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